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Blends of thermoplastic polyurethane and polypropylene. II. Thermal and morphological behavior
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Zeitschriftentitel: | Journal of Applied Polymer Science |
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Personen und Körperschaften: | , , , |
In: | Journal of Applied Polymer Science, 117, 2010, 3, S. 1378-1384 |
Format: | E-Article |
Sprache: | Englisch |
veröffentlicht: |
Wiley
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Schlagwörter: |
author_facet |
Govorčin Bajsić, Emi Pustak, Anđela Šmit, Ivan Leskovac, Mirela Govorčin Bajsić, Emi Pustak, Anđela Šmit, Ivan Leskovac, Mirela |
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author |
Govorčin Bajsić, Emi Pustak, Anđela Šmit, Ivan Leskovac, Mirela |
spellingShingle |
Govorčin Bajsić, Emi Pustak, Anđela Šmit, Ivan Leskovac, Mirela Journal of Applied Polymer Science Blends of thermoplastic polyurethane and polypropylene. II. Thermal and morphological behavior Materials Chemistry Polymers and Plastics Surfaces, Coatings and Films General Chemistry |
author_sort |
govorčin bajsić, emi |
spelling |
Govorčin Bajsić, Emi Pustak, Anđela Šmit, Ivan Leskovac, Mirela 0021-8995 1097-4628 Wiley Materials Chemistry Polymers and Plastics Surfaces, Coatings and Films General Chemistry http://dx.doi.org/10.1002/app.31997 <jats:title>Abstract</jats:title><jats:p>Neat thermoplastic polyurethane (TPU), polypropylene (PP), and TPU/PP blends with different weight ratios that were prepared in a twin‐screw extruder were investigated with differential scanning calorimetry and light and scanning electron microscopy. The results confirmed PP matrix to TPU matrix phase inversion in the concentration region between 60/40 and 80/20 TPU/PP blends. The total degree of crystallinity of the blends and the crystallization temperature of PP decreased with increasing TPU content. On the other hand, the addition of elastomeric TPU to PP significantly increased the spherulite size of PP. The TPU melt islands in the PP matrix prolonged the crystallization of PP during solidification, and this enhanced the growth of spherulites. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010</jats:p> Blends of thermoplastic polyurethane and polypropylene. II. Thermal and morphological behavior Journal of Applied Polymer Science |
doi_str_mv |
10.1002/app.31997 |
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title |
Blends of thermoplastic polyurethane and polypropylene. II. Thermal and morphological behavior |
title_unstemmed |
Blends of thermoplastic polyurethane and polypropylene. II. Thermal and morphological behavior |
title_full |
Blends of thermoplastic polyurethane and polypropylene. II. Thermal and morphological behavior |
title_fullStr |
Blends of thermoplastic polyurethane and polypropylene. II. Thermal and morphological behavior |
title_full_unstemmed |
Blends of thermoplastic polyurethane and polypropylene. II. Thermal and morphological behavior |
title_short |
Blends of thermoplastic polyurethane and polypropylene. II. Thermal and morphological behavior |
title_sort |
blends of thermoplastic polyurethane and polypropylene. ii. thermal and morphological behavior |
topic |
Materials Chemistry Polymers and Plastics Surfaces, Coatings and Films General Chemistry |
url |
http://dx.doi.org/10.1002/app.31997 |
publishDate |
2010 |
physical |
1378-1384 |
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<jats:title>Abstract</jats:title><jats:p>Neat thermoplastic polyurethane (TPU), polypropylene (PP), and TPU/PP blends with different weight ratios that were prepared in a twin‐screw extruder were investigated with differential scanning calorimetry and light and scanning electron microscopy. The results confirmed PP matrix to TPU matrix phase inversion in the concentration region between 60/40 and 80/20 TPU/PP blends. The total degree of crystallinity of the blends and the crystallization temperature of PP decreased with increasing TPU content. On the other hand, the addition of elastomeric TPU to PP significantly increased the spherulite size of PP. The TPU melt islands in the PP matrix prolonged the crystallization of PP during solidification, and this enhanced the growth of spherulites. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010</jats:p> |
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author | Govorčin Bajsić, Emi, Pustak, Anđela, Šmit, Ivan, Leskovac, Mirela |
author_facet | Govorčin Bajsić, Emi, Pustak, Anđela, Šmit, Ivan, Leskovac, Mirela, Govorčin Bajsić, Emi, Pustak, Anđela, Šmit, Ivan, Leskovac, Mirela |
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description | <jats:title>Abstract</jats:title><jats:p>Neat thermoplastic polyurethane (TPU), polypropylene (PP), and TPU/PP blends with different weight ratios that were prepared in a twin‐screw extruder were investigated with differential scanning calorimetry and light and scanning electron microscopy. The results confirmed PP matrix to TPU matrix phase inversion in the concentration region between 60/40 and 80/20 TPU/PP blends. The total degree of crystallinity of the blends and the crystallization temperature of PP decreased with increasing TPU content. On the other hand, the addition of elastomeric TPU to PP significantly increased the spherulite size of PP. The TPU melt islands in the PP matrix prolonged the crystallization of PP during solidification, and this enhanced the growth of spherulites. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010</jats:p> |
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spelling | Govorčin Bajsić, Emi Pustak, Anđela Šmit, Ivan Leskovac, Mirela 0021-8995 1097-4628 Wiley Materials Chemistry Polymers and Plastics Surfaces, Coatings and Films General Chemistry http://dx.doi.org/10.1002/app.31997 <jats:title>Abstract</jats:title><jats:p>Neat thermoplastic polyurethane (TPU), polypropylene (PP), and TPU/PP blends with different weight ratios that were prepared in a twin‐screw extruder were investigated with differential scanning calorimetry and light and scanning electron microscopy. The results confirmed PP matrix to TPU matrix phase inversion in the concentration region between 60/40 and 80/20 TPU/PP blends. The total degree of crystallinity of the blends and the crystallization temperature of PP decreased with increasing TPU content. On the other hand, the addition of elastomeric TPU to PP significantly increased the spherulite size of PP. The TPU melt islands in the PP matrix prolonged the crystallization of PP during solidification, and this enhanced the growth of spherulites. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010</jats:p> Blends of thermoplastic polyurethane and polypropylene. II. Thermal and morphological behavior Journal of Applied Polymer Science |
spellingShingle | Govorčin Bajsić, Emi, Pustak, Anđela, Šmit, Ivan, Leskovac, Mirela, Journal of Applied Polymer Science, Blends of thermoplastic polyurethane and polypropylene. II. Thermal and morphological behavior, Materials Chemistry, Polymers and Plastics, Surfaces, Coatings and Films, General Chemistry |
title | Blends of thermoplastic polyurethane and polypropylene. II. Thermal and morphological behavior |
title_full | Blends of thermoplastic polyurethane and polypropylene. II. Thermal and morphological behavior |
title_fullStr | Blends of thermoplastic polyurethane and polypropylene. II. Thermal and morphological behavior |
title_full_unstemmed | Blends of thermoplastic polyurethane and polypropylene. II. Thermal and morphological behavior |
title_short | Blends of thermoplastic polyurethane and polypropylene. II. Thermal and morphological behavior |
title_sort | blends of thermoplastic polyurethane and polypropylene. ii. thermal and morphological behavior |
title_unstemmed | Blends of thermoplastic polyurethane and polypropylene. II. Thermal and morphological behavior |
topic | Materials Chemistry, Polymers and Plastics, Surfaces, Coatings and Films, General Chemistry |
url | http://dx.doi.org/10.1002/app.31997 |