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Improved dispersion of clay platelets in poly(butylene terephthalate) nanocomposite by ring‐opening polymerization of cyclic oligomers: Effect of the processing conditions and comp...
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| Zeitschriftentitel: | Journal of Applied Polymer Science |
|---|---|
| Personen und Körperschaften: | , , , , , , |
| In: | Journal of Applied Polymer Science, 114, 2009, 5, S. 3211-3217 |
| Format: | E-Article |
| Sprache: | Englisch |
| veröffentlicht: |
Wiley
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| Schlagwörter: |
| author_facet |
Berti, C. Binassi, E. Colonna, M. Fiorini, M. Zuccheri, T. Karanam, S. J. Brunelle, D. Berti, C. Binassi, E. Colonna, M. Fiorini, M. Zuccheri, T. Karanam, S. J. Brunelle, D. |
|---|---|
| author |
Berti, C. Binassi, E. Colonna, M. Fiorini, M. Zuccheri, T. Karanam, S. J. Brunelle, D. |
| spellingShingle |
Berti, C. Binassi, E. Colonna, M. Fiorini, M. Zuccheri, T. Karanam, S. J. Brunelle, D. Journal of Applied Polymer Science Improved dispersion of clay platelets in poly(butylene terephthalate) nanocomposite by ring‐opening polymerization of cyclic oligomers: Effect of the processing conditions and comparison with nanocomposites obtained by melt intercalation Materials Chemistry Polymers and Plastics Surfaces, Coatings and Films General Chemistry |
| author_sort |
berti, c. |
| spelling |
Berti, C. Binassi, E. Colonna, M. Fiorini, M. Zuccheri, T. Karanam, S. J. Brunelle, D. 0021-8995 1097-4628 Wiley Materials Chemistry Polymers and Plastics Surfaces, Coatings and Films General Chemistry http://dx.doi.org/10.1002/app.30957 <jats:title>Abstract</jats:title><jats:p>Poly(butylene terephthalate) nanocomposites with organically modified montmorillonites have been prepared by <jats:italic>in‐situ</jats:italic> ring opening polymerization of PBT cyclic oligomers. High molecular weight polymers can be obtained by choosing the proper polymerization conditions and catalyst in very short polymerization time (10 min) and low temperature (205°C). A better dispersion of the clay and a consistently higher <jats:italic>M</jats:italic><jats:sub>w</jats:sub> have been obtained by this method respect to the standard melt intercalation approach, leading to improved thermo‐mechanical properties of the nanocomposite. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2009</jats:p> Improved dispersion of clay platelets in poly(butylene terephthalate) nanocomposite by ring‐opening polymerization of cyclic oligomers: Effect of the processing conditions and comparison with nanocomposites obtained by melt intercalation Journal of Applied Polymer Science |
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| title |
Improved dispersion of clay platelets in poly(butylene terephthalate) nanocomposite by ring‐opening polymerization of cyclic oligomers: Effect of the processing conditions and comparison with nanocomposites obtained by melt intercalation |
| title_unstemmed |
Improved dispersion of clay platelets in poly(butylene terephthalate) nanocomposite by ring‐opening polymerization of cyclic oligomers: Effect of the processing conditions and comparison with nanocomposites obtained by melt intercalation |
| title_full |
Improved dispersion of clay platelets in poly(butylene terephthalate) nanocomposite by ring‐opening polymerization of cyclic oligomers: Effect of the processing conditions and comparison with nanocomposites obtained by melt intercalation |
| title_fullStr |
Improved dispersion of clay platelets in poly(butylene terephthalate) nanocomposite by ring‐opening polymerization of cyclic oligomers: Effect of the processing conditions and comparison with nanocomposites obtained by melt intercalation |
| title_full_unstemmed |
Improved dispersion of clay platelets in poly(butylene terephthalate) nanocomposite by ring‐opening polymerization of cyclic oligomers: Effect of the processing conditions and comparison with nanocomposites obtained by melt intercalation |
| title_short |
Improved dispersion of clay platelets in poly(butylene terephthalate) nanocomposite by ring‐opening polymerization of cyclic oligomers: Effect of the processing conditions and comparison with nanocomposites obtained by melt intercalation |
| title_sort |
improved dispersion of clay platelets in poly(butylene terephthalate) nanocomposite by ring‐opening polymerization of cyclic oligomers: effect of the processing conditions and comparison with nanocomposites obtained by melt intercalation |
| topic |
Materials Chemistry Polymers and Plastics Surfaces, Coatings and Films General Chemistry |
| url |
http://dx.doi.org/10.1002/app.30957 |
| publishDate |
2009 |
| physical |
3211-3217 |
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<jats:title>Abstract</jats:title><jats:p>Poly(butylene terephthalate) nanocomposites with organically modified montmorillonites have been prepared by <jats:italic>in‐situ</jats:italic> ring opening polymerization of PBT cyclic oligomers. High molecular weight polymers can be obtained by choosing the proper polymerization conditions and catalyst in very short polymerization time (10 min) and low temperature (205°C). A better dispersion of the clay and a consistently higher <jats:italic>M</jats:italic><jats:sub>w</jats:sub> have been obtained by this method respect to the standard melt intercalation approach, leading to improved thermo‐mechanical properties of the nanocomposite. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2009</jats:p> |
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| author | Berti, C., Binassi, E., Colonna, M., Fiorini, M., Zuccheri, T., Karanam, S., J. Brunelle, D. |
| author_facet | Berti, C., Binassi, E., Colonna, M., Fiorini, M., Zuccheri, T., Karanam, S., J. Brunelle, D., Berti, C., Binassi, E., Colonna, M., Fiorini, M., Zuccheri, T., Karanam, S., J. Brunelle, D. |
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| description | <jats:title>Abstract</jats:title><jats:p>Poly(butylene terephthalate) nanocomposites with organically modified montmorillonites have been prepared by <jats:italic>in‐situ</jats:italic> ring opening polymerization of PBT cyclic oligomers. High molecular weight polymers can be obtained by choosing the proper polymerization conditions and catalyst in very short polymerization time (10 min) and low temperature (205°C). A better dispersion of the clay and a consistently higher <jats:italic>M</jats:italic><jats:sub>w</jats:sub> have been obtained by this method respect to the standard melt intercalation approach, leading to improved thermo‐mechanical properties of the nanocomposite. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2009</jats:p> |
| doi_str_mv | 10.1002/app.30957 |
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| institution | DE-D275, DE-Bn3, DE-Brt1, DE-D161, DE-Gla1, DE-Zi4, DE-15, DE-Pl11, DE-Rs1, DE-105, DE-14, DE-Ch1, DE-L229 |
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| physical | 3211-3217 |
| publishDate | 2009 |
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| series | Journal of Applied Polymer Science |
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| spelling | Berti, C. Binassi, E. Colonna, M. Fiorini, M. Zuccheri, T. Karanam, S. J. Brunelle, D. 0021-8995 1097-4628 Wiley Materials Chemistry Polymers and Plastics Surfaces, Coatings and Films General Chemistry http://dx.doi.org/10.1002/app.30957 <jats:title>Abstract</jats:title><jats:p>Poly(butylene terephthalate) nanocomposites with organically modified montmorillonites have been prepared by <jats:italic>in‐situ</jats:italic> ring opening polymerization of PBT cyclic oligomers. High molecular weight polymers can be obtained by choosing the proper polymerization conditions and catalyst in very short polymerization time (10 min) and low temperature (205°C). A better dispersion of the clay and a consistently higher <jats:italic>M</jats:italic><jats:sub>w</jats:sub> have been obtained by this method respect to the standard melt intercalation approach, leading to improved thermo‐mechanical properties of the nanocomposite. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2009</jats:p> Improved dispersion of clay platelets in poly(butylene terephthalate) nanocomposite by ring‐opening polymerization of cyclic oligomers: Effect of the processing conditions and comparison with nanocomposites obtained by melt intercalation Journal of Applied Polymer Science |
| spellingShingle | Berti, C., Binassi, E., Colonna, M., Fiorini, M., Zuccheri, T., Karanam, S., J. Brunelle, D., Journal of Applied Polymer Science, Improved dispersion of clay platelets in poly(butylene terephthalate) nanocomposite by ring‐opening polymerization of cyclic oligomers: Effect of the processing conditions and comparison with nanocomposites obtained by melt intercalation, Materials Chemistry, Polymers and Plastics, Surfaces, Coatings and Films, General Chemistry |
| title | Improved dispersion of clay platelets in poly(butylene terephthalate) nanocomposite by ring‐opening polymerization of cyclic oligomers: Effect of the processing conditions and comparison with nanocomposites obtained by melt intercalation |
| title_full | Improved dispersion of clay platelets in poly(butylene terephthalate) nanocomposite by ring‐opening polymerization of cyclic oligomers: Effect of the processing conditions and comparison with nanocomposites obtained by melt intercalation |
| title_fullStr | Improved dispersion of clay platelets in poly(butylene terephthalate) nanocomposite by ring‐opening polymerization of cyclic oligomers: Effect of the processing conditions and comparison with nanocomposites obtained by melt intercalation |
| title_full_unstemmed | Improved dispersion of clay platelets in poly(butylene terephthalate) nanocomposite by ring‐opening polymerization of cyclic oligomers: Effect of the processing conditions and comparison with nanocomposites obtained by melt intercalation |
| title_short | Improved dispersion of clay platelets in poly(butylene terephthalate) nanocomposite by ring‐opening polymerization of cyclic oligomers: Effect of the processing conditions and comparison with nanocomposites obtained by melt intercalation |
| title_sort | improved dispersion of clay platelets in poly(butylene terephthalate) nanocomposite by ring‐opening polymerization of cyclic oligomers: effect of the processing conditions and comparison with nanocomposites obtained by melt intercalation |
| title_unstemmed | Improved dispersion of clay platelets in poly(butylene terephthalate) nanocomposite by ring‐opening polymerization of cyclic oligomers: Effect of the processing conditions and comparison with nanocomposites obtained by melt intercalation |
| topic | Materials Chemistry, Polymers and Plastics, Surfaces, Coatings and Films, General Chemistry |
| url | http://dx.doi.org/10.1002/app.30957 |