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The use of sol‐gel analysis to estimate chain scission during vulcanization. Part I. Peroxide vulcanization of natural rubber
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| Zeitschriftentitel: | Journal of Applied Polymer Science |
|---|---|
| Personen und Körperschaften: | |
| In: | Journal of Applied Polymer Science, 7, 1963, 3, S. 1023-1030 |
| Format: | E-Article |
| Sprache: | Englisch |
| veröffentlicht: |
Wiley
|
| Schlagwörter: |
| author_facet |
Bristow, G. M. Bristow, G. M. |
|---|---|
| author |
Bristow, G. M. |
| spellingShingle |
Bristow, G. M. Journal of Applied Polymer Science The use of sol‐gel analysis to estimate chain scission during vulcanization. Part I. Peroxide vulcanization of natural rubber Materials Chemistry Polymers and Plastics Surfaces, Coatings and Films General Chemistry |
| author_sort |
bristow, g. m. |
| spelling |
Bristow, G. M. 0021-8995 1097-4628 Wiley Materials Chemistry Polymers and Plastics Surfaces, Coatings and Films General Chemistry http://dx.doi.org/10.1002/app.1963.070070319 <jats:title>Abstract</jats:title><jats:p>Sol‐gel analysis, that is, the measurement of the fraction of rubber remaining unconnected to the network as a function of the degree of cure, has been used to estimate the extent of chain scission in the vulcanization of natural rubber with dicumyl peroxide at 130°C. For peroxide concentrations in the range 1–5% and masticated rubbers of <jats:italic>M̄</jats:italic><jats:sub>n</jats:sub> = 0.84–2.67 × 10<jats:sup>5</jats:sup> there are only 1–3 sites of scission per 100 crosslinked isoprene units.</jats:p> The use of sol‐gel analysis to estimate chain scission during vulcanization. Part I. Peroxide vulcanization of natural rubber Journal of Applied Polymer Science |
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Wiley, 1963 |
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Journal of Applied Polymer Science |
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| title |
The use of sol‐gel analysis to estimate chain scission during vulcanization. Part I. Peroxide vulcanization of natural rubber |
| title_unstemmed |
The use of sol‐gel analysis to estimate chain scission during vulcanization. Part I. Peroxide vulcanization of natural rubber |
| title_full |
The use of sol‐gel analysis to estimate chain scission during vulcanization. Part I. Peroxide vulcanization of natural rubber |
| title_fullStr |
The use of sol‐gel analysis to estimate chain scission during vulcanization. Part I. Peroxide vulcanization of natural rubber |
| title_full_unstemmed |
The use of sol‐gel analysis to estimate chain scission during vulcanization. Part I. Peroxide vulcanization of natural rubber |
| title_short |
The use of sol‐gel analysis to estimate chain scission during vulcanization. Part I. Peroxide vulcanization of natural rubber |
| title_sort |
the use of sol‐gel analysis to estimate chain scission during vulcanization. part i. peroxide vulcanization of natural rubber |
| topic |
Materials Chemistry Polymers and Plastics Surfaces, Coatings and Films General Chemistry |
| url |
http://dx.doi.org/10.1002/app.1963.070070319 |
| publishDate |
1963 |
| physical |
1023-1030 |
| description |
<jats:title>Abstract</jats:title><jats:p>Sol‐gel analysis, that is, the measurement of the fraction of rubber remaining unconnected to the network as a function of the degree of cure, has been used to estimate the extent of chain scission in the vulcanization of natural rubber with dicumyl peroxide at 130°C. For peroxide concentrations in the range 1–5% and masticated rubbers of <jats:italic>M̄</jats:italic><jats:sub>n</jats:sub> = 0.84–2.67 × 10<jats:sup>5</jats:sup> there are only 1–3 sites of scission per 100 crosslinked isoprene units.</jats:p> |
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| description | <jats:title>Abstract</jats:title><jats:p>Sol‐gel analysis, that is, the measurement of the fraction of rubber remaining unconnected to the network as a function of the degree of cure, has been used to estimate the extent of chain scission in the vulcanization of natural rubber with dicumyl peroxide at 130°C. For peroxide concentrations in the range 1–5% and masticated rubbers of <jats:italic>M̄</jats:italic><jats:sub>n</jats:sub> = 0.84–2.67 × 10<jats:sup>5</jats:sup> there are only 1–3 sites of scission per 100 crosslinked isoprene units.</jats:p> |
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| imprint | Wiley, 1963 |
| imprint_str_mv | Wiley, 1963 |
| institution | DE-105, DE-14, DE-Ch1, DE-L229, DE-D275, DE-Bn3, DE-Brt1, DE-D161, DE-Gla1, DE-Zi4, DE-15, DE-Rs1, DE-Pl11 |
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| physical | 1023-1030 |
| publishDate | 1963 |
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| series | Journal of Applied Polymer Science |
| source_id | 49 |
| spelling | Bristow, G. M. 0021-8995 1097-4628 Wiley Materials Chemistry Polymers and Plastics Surfaces, Coatings and Films General Chemistry http://dx.doi.org/10.1002/app.1963.070070319 <jats:title>Abstract</jats:title><jats:p>Sol‐gel analysis, that is, the measurement of the fraction of rubber remaining unconnected to the network as a function of the degree of cure, has been used to estimate the extent of chain scission in the vulcanization of natural rubber with dicumyl peroxide at 130°C. For peroxide concentrations in the range 1–5% and masticated rubbers of <jats:italic>M̄</jats:italic><jats:sub>n</jats:sub> = 0.84–2.67 × 10<jats:sup>5</jats:sup> there are only 1–3 sites of scission per 100 crosslinked isoprene units.</jats:p> The use of sol‐gel analysis to estimate chain scission during vulcanization. Part I. Peroxide vulcanization of natural rubber Journal of Applied Polymer Science |
| spellingShingle | Bristow, G. M., Journal of Applied Polymer Science, The use of sol‐gel analysis to estimate chain scission during vulcanization. Part I. Peroxide vulcanization of natural rubber, Materials Chemistry, Polymers and Plastics, Surfaces, Coatings and Films, General Chemistry |
| title | The use of sol‐gel analysis to estimate chain scission during vulcanization. Part I. Peroxide vulcanization of natural rubber |
| title_full | The use of sol‐gel analysis to estimate chain scission during vulcanization. Part I. Peroxide vulcanization of natural rubber |
| title_fullStr | The use of sol‐gel analysis to estimate chain scission during vulcanization. Part I. Peroxide vulcanization of natural rubber |
| title_full_unstemmed | The use of sol‐gel analysis to estimate chain scission during vulcanization. Part I. Peroxide vulcanization of natural rubber |
| title_short | The use of sol‐gel analysis to estimate chain scission during vulcanization. Part I. Peroxide vulcanization of natural rubber |
| title_sort | the use of sol‐gel analysis to estimate chain scission during vulcanization. part i. peroxide vulcanization of natural rubber |
| title_unstemmed | The use of sol‐gel analysis to estimate chain scission during vulcanization. Part I. Peroxide vulcanization of natural rubber |
| topic | Materials Chemistry, Polymers and Plastics, Surfaces, Coatings and Films, General Chemistry |
| url | http://dx.doi.org/10.1002/app.1963.070070319 |