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Rhodium‐Catalyzed C(sp2)‐ or C(sp3)−H Bond Functionalization Assisted by Removable Directing Groups
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| Zeitschriftentitel: | Angewandte Chemie International Edition |
|---|---|
| Personen und Körperschaften: | , |
| In: | Angewandte Chemie International Edition, 58, 2019, 25, S. 8304-8329 |
| Format: | E-Article |
| Sprache: | Englisch |
| veröffentlicht: |
Wiley
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| Schlagwörter: |
| author_facet |
Rej, Supriya Chatani, Naoto Rej, Supriya Chatani, Naoto |
|---|---|
| author |
Rej, Supriya Chatani, Naoto |
| spellingShingle |
Rej, Supriya Chatani, Naoto Angewandte Chemie International Edition Rhodium‐Catalyzed C(sp2)‐ or C(sp3)−H Bond Functionalization Assisted by Removable Directing Groups General Chemistry Catalysis |
| author_sort |
rej, supriya |
| spelling |
Rej, Supriya Chatani, Naoto 1433-7851 1521-3773 Wiley General Chemistry Catalysis http://dx.doi.org/10.1002/anie.201808159 <jats:title>Abstract</jats:title><jats:p>In recent years, transition‐metal‐catalyzed C−H activation has become a key strategy in the field of organic synthesis. Rhodium complexes are widely used as catalysts in a variety of C−H functionalization reactions because of their high reactivity and selectivity. The availability of a number of rhodium complexes in various oxidation states enables diverse reaction patterns to be obtained. Regioselectivity, an important issue in C−H activation chemistry, can be accomplished by using a directing group to assist the reaction. However, to obtain the target functionalized compounds, it is also necessary to use a directing group that can be easily removed. A wide range of directed C−H functionalization reactions catalyzed by rhodium complexes have been reported to date. In this Review, we discuss Rh‐catalyzed C−H functionalization reactions that are aided by the use of a removable directing group such as phenol, amine, aldehyde, ketones, ester, acid, sulfonic acid, and N‐heteroaromatic derivatives.</jats:p> Rhodium‐Catalyzed C(sp<sup>2</sup>)‐ or C(sp<sup>3</sup>)−H Bond Functionalization Assisted by Removable Directing Groups Angewandte Chemie International Edition |
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| title |
Rhodium‐Catalyzed C(sp2)‐ or C(sp3)−H Bond Functionalization Assisted by Removable Directing Groups |
| title_unstemmed |
Rhodium‐Catalyzed C(sp2)‐ or C(sp3)−H Bond Functionalization Assisted by Removable Directing Groups |
| title_full |
Rhodium‐Catalyzed C(sp2)‐ or C(sp3)−H Bond Functionalization Assisted by Removable Directing Groups |
| title_fullStr |
Rhodium‐Catalyzed C(sp2)‐ or C(sp3)−H Bond Functionalization Assisted by Removable Directing Groups |
| title_full_unstemmed |
Rhodium‐Catalyzed C(sp2)‐ or C(sp3)−H Bond Functionalization Assisted by Removable Directing Groups |
| title_short |
Rhodium‐Catalyzed C(sp2)‐ or C(sp3)−H Bond Functionalization Assisted by Removable Directing Groups |
| title_sort |
rhodium‐catalyzed c(sp<sup>2</sup>)‐ or c(sp<sup>3</sup>)−h bond functionalization assisted by removable directing groups |
| topic |
General Chemistry Catalysis |
| url |
http://dx.doi.org/10.1002/anie.201808159 |
| publishDate |
2019 |
| physical |
8304-8329 |
| description |
<jats:title>Abstract</jats:title><jats:p>In recent years, transition‐metal‐catalyzed C−H activation has become a key strategy in the field of organic synthesis. Rhodium complexes are widely used as catalysts in a variety of C−H functionalization reactions because of their high reactivity and selectivity. The availability of a number of rhodium complexes in various oxidation states enables diverse reaction patterns to be obtained. Regioselectivity, an important issue in C−H activation chemistry, can be accomplished by using a directing group to assist the reaction. However, to obtain the target functionalized compounds, it is also necessary to use a directing group that can be easily removed. A wide range of directed C−H functionalization reactions catalyzed by rhodium complexes have been reported to date. In this Review, we discuss Rh‐catalyzed C−H functionalization reactions that are aided by the use of a removable directing group such as phenol, amine, aldehyde, ketones, ester, acid, sulfonic acid, and N‐heteroaromatic derivatives.</jats:p> |
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| description | <jats:title>Abstract</jats:title><jats:p>In recent years, transition‐metal‐catalyzed C−H activation has become a key strategy in the field of organic synthesis. Rhodium complexes are widely used as catalysts in a variety of C−H functionalization reactions because of their high reactivity and selectivity. The availability of a number of rhodium complexes in various oxidation states enables diverse reaction patterns to be obtained. Regioselectivity, an important issue in C−H activation chemistry, can be accomplished by using a directing group to assist the reaction. However, to obtain the target functionalized compounds, it is also necessary to use a directing group that can be easily removed. A wide range of directed C−H functionalization reactions catalyzed by rhodium complexes have been reported to date. In this Review, we discuss Rh‐catalyzed C−H functionalization reactions that are aided by the use of a removable directing group such as phenol, amine, aldehyde, ketones, ester, acid, sulfonic acid, and N‐heteroaromatic derivatives.</jats:p> |
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| imprint_str_mv | Wiley, 2019 |
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| spelling | Rej, Supriya Chatani, Naoto 1433-7851 1521-3773 Wiley General Chemistry Catalysis http://dx.doi.org/10.1002/anie.201808159 <jats:title>Abstract</jats:title><jats:p>In recent years, transition‐metal‐catalyzed C−H activation has become a key strategy in the field of organic synthesis. Rhodium complexes are widely used as catalysts in a variety of C−H functionalization reactions because of their high reactivity and selectivity. The availability of a number of rhodium complexes in various oxidation states enables diverse reaction patterns to be obtained. Regioselectivity, an important issue in C−H activation chemistry, can be accomplished by using a directing group to assist the reaction. However, to obtain the target functionalized compounds, it is also necessary to use a directing group that can be easily removed. A wide range of directed C−H functionalization reactions catalyzed by rhodium complexes have been reported to date. In this Review, we discuss Rh‐catalyzed C−H functionalization reactions that are aided by the use of a removable directing group such as phenol, amine, aldehyde, ketones, ester, acid, sulfonic acid, and N‐heteroaromatic derivatives.</jats:p> Rhodium‐Catalyzed C(sp<sup>2</sup>)‐ or C(sp<sup>3</sup>)−H Bond Functionalization Assisted by Removable Directing Groups Angewandte Chemie International Edition |
| spellingShingle | Rej, Supriya, Chatani, Naoto, Angewandte Chemie International Edition, Rhodium‐Catalyzed C(sp2)‐ or C(sp3)−H Bond Functionalization Assisted by Removable Directing Groups, General Chemistry, Catalysis |
| title | Rhodium‐Catalyzed C(sp2)‐ or C(sp3)−H Bond Functionalization Assisted by Removable Directing Groups |
| title_full | Rhodium‐Catalyzed C(sp2)‐ or C(sp3)−H Bond Functionalization Assisted by Removable Directing Groups |
| title_fullStr | Rhodium‐Catalyzed C(sp2)‐ or C(sp3)−H Bond Functionalization Assisted by Removable Directing Groups |
| title_full_unstemmed | Rhodium‐Catalyzed C(sp2)‐ or C(sp3)−H Bond Functionalization Assisted by Removable Directing Groups |
| title_short | Rhodium‐Catalyzed C(sp2)‐ or C(sp3)−H Bond Functionalization Assisted by Removable Directing Groups |
| title_sort | rhodium‐catalyzed c(sp<sup>2</sup>)‐ or c(sp<sup>3</sup>)−h bond functionalization assisted by removable directing groups |
| title_unstemmed | Rhodium‐Catalyzed C(sp2)‐ or C(sp3)−H Bond Functionalization Assisted by Removable Directing Groups |
| topic | General Chemistry, Catalysis |
| url | http://dx.doi.org/10.1002/anie.201808159 |