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A Stable Monomeric SiO2 Complex with Donor–Acceptor Ligands
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| Zeitschriftentitel: | Angewandte Chemie International Edition |
|---|---|
| Personen und Körperschaften: | , , , , , , |
| In: | Angewandte Chemie International Edition, 56, 2017, 14, S. 3935-3939 |
| Format: | E-Article |
| Sprache: | Englisch |
| veröffentlicht: |
Wiley
|
| Schlagwörter: |
| author_facet |
Rodriguez, Ricardo Gau, David Saouli, Jérémy Baceiredo, Antoine Saffon‐Merceron, Nathalie Branchadell, Vicenç Kato, Tsuyoshi Rodriguez, Ricardo Gau, David Saouli, Jérémy Baceiredo, Antoine Saffon‐Merceron, Nathalie Branchadell, Vicenç Kato, Tsuyoshi |
|---|---|
| author |
Rodriguez, Ricardo Gau, David Saouli, Jérémy Baceiredo, Antoine Saffon‐Merceron, Nathalie Branchadell, Vicenç Kato, Tsuyoshi |
| spellingShingle |
Rodriguez, Ricardo Gau, David Saouli, Jérémy Baceiredo, Antoine Saffon‐Merceron, Nathalie Branchadell, Vicenç Kato, Tsuyoshi Angewandte Chemie International Edition A Stable Monomeric SiO2 Complex with Donor–Acceptor Ligands General Chemistry Catalysis |
| author_sort |
rodriguez, ricardo |
| spelling |
Rodriguez, Ricardo Gau, David Saouli, Jérémy Baceiredo, Antoine Saffon‐Merceron, Nathalie Branchadell, Vicenç Kato, Tsuyoshi 1433-7851 1521-3773 Wiley General Chemistry Catalysis http://dx.doi.org/10.1002/anie.201611851 <jats:title>Abstract</jats:title><jats:p>Isolation of a monomeric SiO<jats:sub>2</jats:sub> compound <jats:bold>3</jats:bold> as a stable donor–acceptor complex with two different ligands —a σ‐donating ligand (pyridine, dimethylaminopyridine, <jats:italic>N</jats:italic>‐heterocyclic carbene) and a donor–acceptor ligand (iminophosphorane)—is presented. The SiO<jats:sub>2</jats:sub> complex <jats:bold>3</jats:bold> is soluble in ordinary organic solvents and is stable at room temperature in solution and in the solid state. Of particular interest, <jats:bold>3</jats:bold> remains reactive and can be used as a stable and soluble unimolecular SiO<jats:sub>2</jats:sub> reagent.</jats:p> A Stable Monomeric SiO<sub>2</sub> Complex with Donor–Acceptor Ligands Angewandte Chemie International Edition |
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10.1002/anie.201611851 |
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Online |
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Chemie und Pharmazie |
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Wiley, 2017 |
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Wiley, 2017 |
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1433-7851 1521-3773 |
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2017 |
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Wiley |
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ai |
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Angewandte Chemie International Edition |
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| title |
A Stable Monomeric SiO2 Complex with Donor–Acceptor Ligands |
| title_unstemmed |
A Stable Monomeric SiO2 Complex with Donor–Acceptor Ligands |
| title_full |
A Stable Monomeric SiO2 Complex with Donor–Acceptor Ligands |
| title_fullStr |
A Stable Monomeric SiO2 Complex with Donor–Acceptor Ligands |
| title_full_unstemmed |
A Stable Monomeric SiO2 Complex with Donor–Acceptor Ligands |
| title_short |
A Stable Monomeric SiO2 Complex with Donor–Acceptor Ligands |
| title_sort |
a stable monomeric sio<sub>2</sub> complex with donor–acceptor ligands |
| topic |
General Chemistry Catalysis |
| url |
http://dx.doi.org/10.1002/anie.201611851 |
| publishDate |
2017 |
| physical |
3935-3939 |
| description |
<jats:title>Abstract</jats:title><jats:p>Isolation of a monomeric SiO<jats:sub>2</jats:sub> compound <jats:bold>3</jats:bold> as a stable donor–acceptor complex with two different ligands —a σ‐donating ligand (pyridine, dimethylaminopyridine, <jats:italic>N</jats:italic>‐heterocyclic carbene) and a donor–acceptor ligand (iminophosphorane)—is presented. The SiO<jats:sub>2</jats:sub> complex <jats:bold>3</jats:bold> is soluble in ordinary organic solvents and is stable at room temperature in solution and in the solid state. Of particular interest, <jats:bold>3</jats:bold> remains reactive and can be used as a stable and soluble unimolecular SiO<jats:sub>2</jats:sub> reagent.</jats:p> |
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| _version_ | 1792345294141128711 |
| author | Rodriguez, Ricardo, Gau, David, Saouli, Jérémy, Baceiredo, Antoine, Saffon‐Merceron, Nathalie, Branchadell, Vicenç, Kato, Tsuyoshi |
| author_facet | Rodriguez, Ricardo, Gau, David, Saouli, Jérémy, Baceiredo, Antoine, Saffon‐Merceron, Nathalie, Branchadell, Vicenç, Kato, Tsuyoshi, Rodriguez, Ricardo, Gau, David, Saouli, Jérémy, Baceiredo, Antoine, Saffon‐Merceron, Nathalie, Branchadell, Vicenç, Kato, Tsuyoshi |
| author_sort | rodriguez, ricardo |
| container_issue | 14 |
| container_start_page | 3935 |
| container_title | Angewandte Chemie International Edition |
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| description | <jats:title>Abstract</jats:title><jats:p>Isolation of a monomeric SiO<jats:sub>2</jats:sub> compound <jats:bold>3</jats:bold> as a stable donor–acceptor complex with two different ligands —a σ‐donating ligand (pyridine, dimethylaminopyridine, <jats:italic>N</jats:italic>‐heterocyclic carbene) and a donor–acceptor ligand (iminophosphorane)—is presented. The SiO<jats:sub>2</jats:sub> complex <jats:bold>3</jats:bold> is soluble in ordinary organic solvents and is stable at room temperature in solution and in the solid state. Of particular interest, <jats:bold>3</jats:bold> remains reactive and can be used as a stable and soluble unimolecular SiO<jats:sub>2</jats:sub> reagent.</jats:p> |
| doi_str_mv | 10.1002/anie.201611851 |
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| imprint | Wiley, 2017 |
| imprint_str_mv | Wiley, 2017 |
| institution | DE-D275, DE-Bn3, DE-Brt1, DE-D161, DE-Zi4, DE-Gla1, DE-15, DE-Pl11, DE-Rs1, DE-14, DE-105, DE-Ch1, DE-L229 |
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| issn_str_mv | 1433-7851, 1521-3773 |
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| physical | 3935-3939 |
| publishDate | 2017 |
| publishDateSort | 2017 |
| publisher | Wiley |
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| recordtype | ai |
| series | Angewandte Chemie International Edition |
| source_id | 49 |
| spelling | Rodriguez, Ricardo Gau, David Saouli, Jérémy Baceiredo, Antoine Saffon‐Merceron, Nathalie Branchadell, Vicenç Kato, Tsuyoshi 1433-7851 1521-3773 Wiley General Chemistry Catalysis http://dx.doi.org/10.1002/anie.201611851 <jats:title>Abstract</jats:title><jats:p>Isolation of a monomeric SiO<jats:sub>2</jats:sub> compound <jats:bold>3</jats:bold> as a stable donor–acceptor complex with two different ligands —a σ‐donating ligand (pyridine, dimethylaminopyridine, <jats:italic>N</jats:italic>‐heterocyclic carbene) and a donor–acceptor ligand (iminophosphorane)—is presented. The SiO<jats:sub>2</jats:sub> complex <jats:bold>3</jats:bold> is soluble in ordinary organic solvents and is stable at room temperature in solution and in the solid state. Of particular interest, <jats:bold>3</jats:bold> remains reactive and can be used as a stable and soluble unimolecular SiO<jats:sub>2</jats:sub> reagent.</jats:p> A Stable Monomeric SiO<sub>2</sub> Complex with Donor–Acceptor Ligands Angewandte Chemie International Edition |
| spellingShingle | Rodriguez, Ricardo, Gau, David, Saouli, Jérémy, Baceiredo, Antoine, Saffon‐Merceron, Nathalie, Branchadell, Vicenç, Kato, Tsuyoshi, Angewandte Chemie International Edition, A Stable Monomeric SiO2 Complex with Donor–Acceptor Ligands, General Chemistry, Catalysis |
| title | A Stable Monomeric SiO2 Complex with Donor–Acceptor Ligands |
| title_full | A Stable Monomeric SiO2 Complex with Donor–Acceptor Ligands |
| title_fullStr | A Stable Monomeric SiO2 Complex with Donor–Acceptor Ligands |
| title_full_unstemmed | A Stable Monomeric SiO2 Complex with Donor–Acceptor Ligands |
| title_short | A Stable Monomeric SiO2 Complex with Donor–Acceptor Ligands |
| title_sort | a stable monomeric sio<sub>2</sub> complex with donor–acceptor ligands |
| title_unstemmed | A Stable Monomeric SiO2 Complex with Donor–Acceptor Ligands |
| topic | General Chemistry, Catalysis |
| url | http://dx.doi.org/10.1002/anie.201611851 |