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Functionalized expanded corn starch‐anchored Cu(I): An efficient and recyclable catalyst for oxidation of 5‐hydroxymethylfurfural to 2,5‐diformylfuran
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| Zeitschriftentitel: | Applied Organometallic Chemistry |
|---|---|
| Personen und Körperschaften: | , , , , , , , , |
| In: | Applied Organometallic Chemistry, 34, 2020, 3 |
| Format: | E-Article |
| Sprache: | Englisch |
| veröffentlicht: |
Wiley
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| Schlagwörter: |
| author_facet |
Hong, Mei Min, Jie Wu, Shuangyan Li, Jiatong Wang, Jing Wei, Lifen Ling, Zhi Li, Kun Wang, Shifa Hong, Mei Min, Jie Wu, Shuangyan Li, Jiatong Wang, Jing Wei, Lifen Ling, Zhi Li, Kun Wang, Shifa |
|---|---|
| author |
Hong, Mei Min, Jie Wu, Shuangyan Li, Jiatong Wang, Jing Wei, Lifen Ling, Zhi Li, Kun Wang, Shifa |
| spellingShingle |
Hong, Mei Min, Jie Wu, Shuangyan Li, Jiatong Wang, Jing Wei, Lifen Ling, Zhi Li, Kun Wang, Shifa Applied Organometallic Chemistry Functionalized expanded corn starch‐anchored Cu(I): An efficient and recyclable catalyst for oxidation of 5‐hydroxymethylfurfural to 2,5‐diformylfuran Inorganic Chemistry General Chemistry |
| author_sort |
hong, mei |
| spelling |
Hong, Mei Min, Jie Wu, Shuangyan Li, Jiatong Wang, Jing Wei, Lifen Ling, Zhi Li, Kun Wang, Shifa 0268-2605 1099-0739 Wiley Inorganic Chemistry General Chemistry http://dx.doi.org/10.1002/aoc.5411 <jats:title>Abstract</jats:title><jats:p>The development of new strategies for the synthesis of biomass‐based non‐precious metal heterogeneous catalysts has recently received great interest from chemists because of the advantages of these catalytic systems being sustainable, low cost and green. An expanded corn starch‐supported CuBr catalyst (ECS‐SB‐CuBr) has been successfully prepared and well characterized using Fourier transform infrared spectroscopy, thermogravimetric analysis, powder X‐ray diffraction, X‐ray photoelectron spectroscopy and scanning electron microscopy/energy‐dispersive X‐ray spectroscopy. Further, ECS‐SB‐CuBr was used as a heterogeneous catalyst for the selective oxidation of 5‐hydroxymethylfurfural (HMF) into 2,5‐diformylfuran (DFF) and a full HMF conversion is obtained with 98% DFF yield in acetonitrile under ambient pressure of dioxygen at 50°C. The catalyst also showed good reusability, could be easily recovered through filtration and washing and was reused in at least six consecutive runs with virtually no loss of catalytic performance.</jats:p> Functionalized expanded corn starch‐anchored Cu(I): An efficient and recyclable catalyst for oxidation of 5‐hydroxymethylfurfural to 2,5‐diformylfuran Applied Organometallic Chemistry |
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Wiley, 2020 |
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| title |
Functionalized expanded corn starch‐anchored Cu(I): An efficient and recyclable catalyst for oxidation of 5‐hydroxymethylfurfural to 2,5‐diformylfuran |
| title_unstemmed |
Functionalized expanded corn starch‐anchored Cu(I): An efficient and recyclable catalyst for oxidation of 5‐hydroxymethylfurfural to 2,5‐diformylfuran |
| title_full |
Functionalized expanded corn starch‐anchored Cu(I): An efficient and recyclable catalyst for oxidation of 5‐hydroxymethylfurfural to 2,5‐diformylfuran |
| title_fullStr |
Functionalized expanded corn starch‐anchored Cu(I): An efficient and recyclable catalyst for oxidation of 5‐hydroxymethylfurfural to 2,5‐diformylfuran |
| title_full_unstemmed |
Functionalized expanded corn starch‐anchored Cu(I): An efficient and recyclable catalyst for oxidation of 5‐hydroxymethylfurfural to 2,5‐diformylfuran |
| title_short |
Functionalized expanded corn starch‐anchored Cu(I): An efficient and recyclable catalyst for oxidation of 5‐hydroxymethylfurfural to 2,5‐diformylfuran |
| title_sort |
functionalized expanded corn starch‐anchored cu(i): an efficient and recyclable catalyst for oxidation of 5‐hydroxymethylfurfural to 2,5‐diformylfuran |
| topic |
Inorganic Chemistry General Chemistry |
| url |
http://dx.doi.org/10.1002/aoc.5411 |
| publishDate |
2020 |
| physical |
|
| description |
<jats:title>Abstract</jats:title><jats:p>The development of new strategies for the synthesis of biomass‐based non‐precious metal heterogeneous catalysts has recently received great interest from chemists because of the advantages of these catalytic systems being sustainable, low cost and green. An expanded corn starch‐supported CuBr catalyst (ECS‐SB‐CuBr) has been successfully prepared and well characterized using Fourier transform infrared spectroscopy, thermogravimetric analysis, powder X‐ray diffraction, X‐ray photoelectron spectroscopy and scanning electron microscopy/energy‐dispersive X‐ray spectroscopy. Further, ECS‐SB‐CuBr was used as a heterogeneous catalyst for the selective oxidation of 5‐hydroxymethylfurfural (HMF) into 2,5‐diformylfuran (DFF) and a full HMF conversion is obtained with 98% DFF yield in acetonitrile under ambient pressure of dioxygen at 50°C. The catalyst also showed good reusability, could be easily recovered through filtration and washing and was reused in at least six consecutive runs with virtually no loss of catalytic performance.</jats:p> |
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| author | Hong, Mei, Min, Jie, Wu, Shuangyan, Li, Jiatong, Wang, Jing, Wei, Lifen, Ling, Zhi, Li, Kun, Wang, Shifa |
| author_facet | Hong, Mei, Min, Jie, Wu, Shuangyan, Li, Jiatong, Wang, Jing, Wei, Lifen, Ling, Zhi, Li, Kun, Wang, Shifa, Hong, Mei, Min, Jie, Wu, Shuangyan, Li, Jiatong, Wang, Jing, Wei, Lifen, Ling, Zhi, Li, Kun, Wang, Shifa |
| author_sort | hong, mei |
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| description | <jats:title>Abstract</jats:title><jats:p>The development of new strategies for the synthesis of biomass‐based non‐precious metal heterogeneous catalysts has recently received great interest from chemists because of the advantages of these catalytic systems being sustainable, low cost and green. An expanded corn starch‐supported CuBr catalyst (ECS‐SB‐CuBr) has been successfully prepared and well characterized using Fourier transform infrared spectroscopy, thermogravimetric analysis, powder X‐ray diffraction, X‐ray photoelectron spectroscopy and scanning electron microscopy/energy‐dispersive X‐ray spectroscopy. Further, ECS‐SB‐CuBr was used as a heterogeneous catalyst for the selective oxidation of 5‐hydroxymethylfurfural (HMF) into 2,5‐diformylfuran (DFF) and a full HMF conversion is obtained with 98% DFF yield in acetonitrile under ambient pressure of dioxygen at 50°C. The catalyst also showed good reusability, could be easily recovered through filtration and washing and was reused in at least six consecutive runs with virtually no loss of catalytic performance.</jats:p> |
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| spelling | Hong, Mei Min, Jie Wu, Shuangyan Li, Jiatong Wang, Jing Wei, Lifen Ling, Zhi Li, Kun Wang, Shifa 0268-2605 1099-0739 Wiley Inorganic Chemistry General Chemistry http://dx.doi.org/10.1002/aoc.5411 <jats:title>Abstract</jats:title><jats:p>The development of new strategies for the synthesis of biomass‐based non‐precious metal heterogeneous catalysts has recently received great interest from chemists because of the advantages of these catalytic systems being sustainable, low cost and green. An expanded corn starch‐supported CuBr catalyst (ECS‐SB‐CuBr) has been successfully prepared and well characterized using Fourier transform infrared spectroscopy, thermogravimetric analysis, powder X‐ray diffraction, X‐ray photoelectron spectroscopy and scanning electron microscopy/energy‐dispersive X‐ray spectroscopy. Further, ECS‐SB‐CuBr was used as a heterogeneous catalyst for the selective oxidation of 5‐hydroxymethylfurfural (HMF) into 2,5‐diformylfuran (DFF) and a full HMF conversion is obtained with 98% DFF yield in acetonitrile under ambient pressure of dioxygen at 50°C. The catalyst also showed good reusability, could be easily recovered through filtration and washing and was reused in at least six consecutive runs with virtually no loss of catalytic performance.</jats:p> Functionalized expanded corn starch‐anchored Cu(I): An efficient and recyclable catalyst for oxidation of 5‐hydroxymethylfurfural to 2,5‐diformylfuran Applied Organometallic Chemistry |
| spellingShingle | Hong, Mei, Min, Jie, Wu, Shuangyan, Li, Jiatong, Wang, Jing, Wei, Lifen, Ling, Zhi, Li, Kun, Wang, Shifa, Applied Organometallic Chemistry, Functionalized expanded corn starch‐anchored Cu(I): An efficient and recyclable catalyst for oxidation of 5‐hydroxymethylfurfural to 2,5‐diformylfuran, Inorganic Chemistry, General Chemistry |
| title | Functionalized expanded corn starch‐anchored Cu(I): An efficient and recyclable catalyst for oxidation of 5‐hydroxymethylfurfural to 2,5‐diformylfuran |
| title_full | Functionalized expanded corn starch‐anchored Cu(I): An efficient and recyclable catalyst for oxidation of 5‐hydroxymethylfurfural to 2,5‐diformylfuran |
| title_fullStr | Functionalized expanded corn starch‐anchored Cu(I): An efficient and recyclable catalyst for oxidation of 5‐hydroxymethylfurfural to 2,5‐diformylfuran |
| title_full_unstemmed | Functionalized expanded corn starch‐anchored Cu(I): An efficient and recyclable catalyst for oxidation of 5‐hydroxymethylfurfural to 2,5‐diformylfuran |
| title_short | Functionalized expanded corn starch‐anchored Cu(I): An efficient and recyclable catalyst for oxidation of 5‐hydroxymethylfurfural to 2,5‐diformylfuran |
| title_sort | functionalized expanded corn starch‐anchored cu(i): an efficient and recyclable catalyst for oxidation of 5‐hydroxymethylfurfural to 2,5‐diformylfuran |
| title_unstemmed | Functionalized expanded corn starch‐anchored Cu(I): An efficient and recyclable catalyst for oxidation of 5‐hydroxymethylfurfural to 2,5‐diformylfuran |
| topic | Inorganic Chemistry, General Chemistry |
| url | http://dx.doi.org/10.1002/aoc.5411 |