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Evaluation of Ion‐Exchange Kinetic Parameters Using Poly‐o‐anisidine and Poly‐o‐toluidine Sn(IV) Tungstate Nanocomposite Cation Exchangers
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| Zeitschriftentitel: | Advances in Polymer Technology |
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| Personen und Körperschaften: | , |
| In: | Advances in Polymer Technology, 32, 2013, 2 |
| Format: | E-Article |
| Sprache: | Englisch |
| veröffentlicht: |
Wiley
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| Schlagwörter: |
| author_facet |
Khan, Asif Ali Shaheen, Shakeeba Khan, Asif Ali Shaheen, Shakeeba |
|---|---|
| author |
Khan, Asif Ali Shaheen, Shakeeba |
| spellingShingle |
Khan, Asif Ali Shaheen, Shakeeba Advances in Polymer Technology Evaluation of Ion‐Exchange Kinetic Parameters Using Poly‐o‐anisidine and Poly‐o‐toluidine Sn(IV) Tungstate Nanocomposite Cation Exchangers Polymers and Plastics Organic Chemistry General Chemical Engineering |
| author_sort |
khan, asif ali |
| spelling |
Khan, Asif Ali Shaheen, Shakeeba 0730-6679 1098-2329 Wiley Polymers and Plastics Organic Chemistry General Chemical Engineering http://dx.doi.org/10.1002/adv.21346 <jats:title>ABSTRACT</jats:title><jats:p>Organic–inorganic nanocomposites poly‐<jats:italic>o</jats:italic>‐anisidine and poly‐<jats:italic>o</jats:italic>‐toluidine Sn(IV) tungstate were chemically synthesized by mixing organic polymers that is, o‐anisidine and o‐toluidine with inorganic gels of Sn(IV) tungstate in different mixing ratios. Ion‐exchange kinetics for few divalent metal ions was evaluated by particle diffusion‐controlled ion‐exchange phenomenon at four different temperatures. The particle diffusion mechanism was confirmed by linear τ (dimensionless time parameter) versus <jats:italic>t</jats:italic> (time) plots. The exchange processes were controlled by the diffusion of ions within the exchanger particle for the systems under studies. Some physical parameters such as self‐diffusion coefficient (<jats:inline-graphic xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="graphic/adv21346-math-0001.png" xlink:title="urn:x-wiley:07306679:adv21346:equation:adv21346-math-0001" />), energy of activation (<jats:italic>E<jats:sub>a</jats:sub></jats:italic>), and entropy of activation (Δ<jats:italic>S</jats:italic>°) were evaluated under conditions favoring a particle diffusion‐controlled mechanism. © 2013 Wiley Periodicals, Inc. Adv Polym Technol 2013, 32, 21346; View this article online at <jats:ext-link xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="http://wileyonlinelibrary.com">wileyonlinelibrary.com</jats:ext-link>. DOI 10.1002/adv.21346</jats:p> Evaluation of Ion‐Exchange Kinetic Parameters Using Poly‐<i>o</i>‐anisidine and Poly‐<i>o</i>‐toluidine Sn(IV) Tungstate Nanocomposite Cation Exchangers Advances in Polymer Technology |
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| title |
Evaluation of Ion‐Exchange Kinetic Parameters Using Poly‐o‐anisidine and Poly‐o‐toluidine Sn(IV) Tungstate Nanocomposite Cation Exchangers |
| title_unstemmed |
Evaluation of Ion‐Exchange Kinetic Parameters Using Poly‐o‐anisidine and Poly‐o‐toluidine Sn(IV) Tungstate Nanocomposite Cation Exchangers |
| title_full |
Evaluation of Ion‐Exchange Kinetic Parameters Using Poly‐o‐anisidine and Poly‐o‐toluidine Sn(IV) Tungstate Nanocomposite Cation Exchangers |
| title_fullStr |
Evaluation of Ion‐Exchange Kinetic Parameters Using Poly‐o‐anisidine and Poly‐o‐toluidine Sn(IV) Tungstate Nanocomposite Cation Exchangers |
| title_full_unstemmed |
Evaluation of Ion‐Exchange Kinetic Parameters Using Poly‐o‐anisidine and Poly‐o‐toluidine Sn(IV) Tungstate Nanocomposite Cation Exchangers |
| title_short |
Evaluation of Ion‐Exchange Kinetic Parameters Using Poly‐o‐anisidine and Poly‐o‐toluidine Sn(IV) Tungstate Nanocomposite Cation Exchangers |
| title_sort |
evaluation of ion‐exchange kinetic parameters using poly‐<i>o</i>‐anisidine and poly‐<i>o</i>‐toluidine sn(iv) tungstate nanocomposite cation exchangers |
| topic |
Polymers and Plastics Organic Chemistry General Chemical Engineering |
| url |
http://dx.doi.org/10.1002/adv.21346 |
| publishDate |
2013 |
| physical |
|
| description |
<jats:title>ABSTRACT</jats:title><jats:p>Organic–inorganic nanocomposites poly‐<jats:italic>o</jats:italic>‐anisidine and poly‐<jats:italic>o</jats:italic>‐toluidine Sn(IV) tungstate were chemically synthesized by mixing organic polymers that is, o‐anisidine and o‐toluidine with inorganic gels of Sn(IV) tungstate in different mixing ratios. Ion‐exchange kinetics for few divalent metal ions was evaluated by particle diffusion‐controlled ion‐exchange phenomenon at four different temperatures. The particle diffusion mechanism was confirmed by linear τ (dimensionless time parameter) versus <jats:italic>t</jats:italic> (time) plots. The exchange processes were controlled by the diffusion of ions within the exchanger particle for the systems under studies. Some physical parameters such as self‐diffusion coefficient (<jats:inline-graphic xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="graphic/adv21346-math-0001.png" xlink:title="urn:x-wiley:07306679:adv21346:equation:adv21346-math-0001" />), energy of activation (<jats:italic>E<jats:sub>a</jats:sub></jats:italic>), and entropy of activation (Δ<jats:italic>S</jats:italic>°) were evaluated under conditions favoring a particle diffusion‐controlled mechanism. © 2013 Wiley Periodicals, Inc. Adv Polym Technol 2013, 32, 21346; View this article online at <jats:ext-link xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="http://wileyonlinelibrary.com">wileyonlinelibrary.com</jats:ext-link>. DOI 10.1002/adv.21346</jats:p> |
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| author | Khan, Asif Ali, Shaheen, Shakeeba |
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| description | <jats:title>ABSTRACT</jats:title><jats:p>Organic–inorganic nanocomposites poly‐<jats:italic>o</jats:italic>‐anisidine and poly‐<jats:italic>o</jats:italic>‐toluidine Sn(IV) tungstate were chemically synthesized by mixing organic polymers that is, o‐anisidine and o‐toluidine with inorganic gels of Sn(IV) tungstate in different mixing ratios. Ion‐exchange kinetics for few divalent metal ions was evaluated by particle diffusion‐controlled ion‐exchange phenomenon at four different temperatures. The particle diffusion mechanism was confirmed by linear τ (dimensionless time parameter) versus <jats:italic>t</jats:italic> (time) plots. The exchange processes were controlled by the diffusion of ions within the exchanger particle for the systems under studies. Some physical parameters such as self‐diffusion coefficient (<jats:inline-graphic xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="graphic/adv21346-math-0001.png" xlink:title="urn:x-wiley:07306679:adv21346:equation:adv21346-math-0001" />), energy of activation (<jats:italic>E<jats:sub>a</jats:sub></jats:italic>), and entropy of activation (Δ<jats:italic>S</jats:italic>°) were evaluated under conditions favoring a particle diffusion‐controlled mechanism. © 2013 Wiley Periodicals, Inc. Adv Polym Technol 2013, 32, 21346; View this article online at <jats:ext-link xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="http://wileyonlinelibrary.com">wileyonlinelibrary.com</jats:ext-link>. DOI 10.1002/adv.21346</jats:p> |
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| spelling | Khan, Asif Ali Shaheen, Shakeeba 0730-6679 1098-2329 Wiley Polymers and Plastics Organic Chemistry General Chemical Engineering http://dx.doi.org/10.1002/adv.21346 <jats:title>ABSTRACT</jats:title><jats:p>Organic–inorganic nanocomposites poly‐<jats:italic>o</jats:italic>‐anisidine and poly‐<jats:italic>o</jats:italic>‐toluidine Sn(IV) tungstate were chemically synthesized by mixing organic polymers that is, o‐anisidine and o‐toluidine with inorganic gels of Sn(IV) tungstate in different mixing ratios. Ion‐exchange kinetics for few divalent metal ions was evaluated by particle diffusion‐controlled ion‐exchange phenomenon at four different temperatures. The particle diffusion mechanism was confirmed by linear τ (dimensionless time parameter) versus <jats:italic>t</jats:italic> (time) plots. The exchange processes were controlled by the diffusion of ions within the exchanger particle for the systems under studies. Some physical parameters such as self‐diffusion coefficient (<jats:inline-graphic xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="graphic/adv21346-math-0001.png" xlink:title="urn:x-wiley:07306679:adv21346:equation:adv21346-math-0001" />), energy of activation (<jats:italic>E<jats:sub>a</jats:sub></jats:italic>), and entropy of activation (Δ<jats:italic>S</jats:italic>°) were evaluated under conditions favoring a particle diffusion‐controlled mechanism. © 2013 Wiley Periodicals, Inc. Adv Polym Technol 2013, 32, 21346; View this article online at <jats:ext-link xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="http://wileyonlinelibrary.com">wileyonlinelibrary.com</jats:ext-link>. DOI 10.1002/adv.21346</jats:p> Evaluation of Ion‐Exchange Kinetic Parameters Using Poly‐<i>o</i>‐anisidine and Poly‐<i>o</i>‐toluidine Sn(IV) Tungstate Nanocomposite Cation Exchangers Advances in Polymer Technology |
| spellingShingle | Khan, Asif Ali, Shaheen, Shakeeba, Advances in Polymer Technology, Evaluation of Ion‐Exchange Kinetic Parameters Using Poly‐o‐anisidine and Poly‐o‐toluidine Sn(IV) Tungstate Nanocomposite Cation Exchangers, Polymers and Plastics, Organic Chemistry, General Chemical Engineering |
| title | Evaluation of Ion‐Exchange Kinetic Parameters Using Poly‐o‐anisidine and Poly‐o‐toluidine Sn(IV) Tungstate Nanocomposite Cation Exchangers |
| title_full | Evaluation of Ion‐Exchange Kinetic Parameters Using Poly‐o‐anisidine and Poly‐o‐toluidine Sn(IV) Tungstate Nanocomposite Cation Exchangers |
| title_fullStr | Evaluation of Ion‐Exchange Kinetic Parameters Using Poly‐o‐anisidine and Poly‐o‐toluidine Sn(IV) Tungstate Nanocomposite Cation Exchangers |
| title_full_unstemmed | Evaluation of Ion‐Exchange Kinetic Parameters Using Poly‐o‐anisidine and Poly‐o‐toluidine Sn(IV) Tungstate Nanocomposite Cation Exchangers |
| title_short | Evaluation of Ion‐Exchange Kinetic Parameters Using Poly‐o‐anisidine and Poly‐o‐toluidine Sn(IV) Tungstate Nanocomposite Cation Exchangers |
| title_sort | evaluation of ion‐exchange kinetic parameters using poly‐<i>o</i>‐anisidine and poly‐<i>o</i>‐toluidine sn(iv) tungstate nanocomposite cation exchangers |
| title_unstemmed | Evaluation of Ion‐Exchange Kinetic Parameters Using Poly‐o‐anisidine and Poly‐o‐toluidine Sn(IV) Tungstate Nanocomposite Cation Exchangers |
| topic | Polymers and Plastics, Organic Chemistry, General Chemical Engineering |
| url | http://dx.doi.org/10.1002/adv.21346 |