Eintrag weiter verarbeiten
Nitrogen‐Doped Ti3C2 MXene: Mechanism Investigation and Electrochemical Analysis
Gespeichert in:
| Zeitschriftentitel: | Advanced Functional Materials |
|---|---|
| Personen und Körperschaften: | , , , , , , |
| In: | Advanced Functional Materials, 30, 2020, 47 |
| Format: | E-Article |
| Sprache: | Englisch |
| veröffentlicht: |
Wiley
|
| Schlagwörter: |
| author_facet |
Lu, Chengjie Yang, Li Yan, Bingzhen Sun, Liangbo Zhang, Peigen Zhang, Wei Sun, ZhengMing Lu, Chengjie Yang, Li Yan, Bingzhen Sun, Liangbo Zhang, Peigen Zhang, Wei Sun, ZhengMing |
|---|---|
| author |
Lu, Chengjie Yang, Li Yan, Bingzhen Sun, Liangbo Zhang, Peigen Zhang, Wei Sun, ZhengMing |
| spellingShingle |
Lu, Chengjie Yang, Li Yan, Bingzhen Sun, Liangbo Zhang, Peigen Zhang, Wei Sun, ZhengMing Advanced Functional Materials Nitrogen‐Doped Ti3C2 MXene: Mechanism Investigation and Electrochemical Analysis Electrochemistry Condensed Matter Physics Biomaterials Electronic, Optical and Magnetic Materials |
| author_sort |
lu, chengjie |
| spelling |
Lu, Chengjie Yang, Li Yan, Bingzhen Sun, Liangbo Zhang, Peigen Zhang, Wei Sun, ZhengMing 1616-301X 1616-3028 Wiley Electrochemistry Condensed Matter Physics Biomaterials Electronic, Optical and Magnetic Materials http://dx.doi.org/10.1002/adfm.202000852 <jats:title>Abstract</jats:title><jats:p>Nitrogen doping has been proven to be a facile modification strategy to improve the electrochemical performance of 2D MXenes, a group of promising candidates for energy storage applications. However, the underlying mechanisms, especially the positions of nitrogen dopants, and its effect on the electrical properties of MXenes, are still largely unexplored. Herein, a comprehensive study is carried out to disclose the nitrogen doping mechanism in Ti<jats:sub>3</jats:sub>C<jats:sub>2</jats:sub> MXene, by employing theoretical simulation and experimental characterization. Three possible sites are found in Ti<jats:sub>3</jats:sub>C<jats:sub>2</jats:sub>T<jats:italic><jats:sub>x</jats:sub></jats:italic> (T = F, OH, and O) to accommodate the nitrogen dopants: lattice substitution (for carbon), function substitution (for –OH), and surface absorption (on –O). Moreover, electrochemical test results confirm that all the three kinds of nitrogen dopants are favorable for improving the specific capacitance of the Ti<jats:sub>3</jats:sub>C<jats:sub>2</jats:sub> electrode, and the underlying factors are successfully distinguished. By revealing the nitrogen doping mechanisms in Ti<jats:sub>3</jats:sub>C<jats:sub>2</jats:sub> MXene, this work provides theoretical guidelines for modulating the electrochemical properties of MXene materials for energy storage applications.</jats:p> Nitrogen‐Doped Ti<sub>3</sub>C<sub>2</sub> MXene: Mechanism Investigation and Electrochemical Analysis Advanced Functional Materials |
| doi_str_mv |
10.1002/adfm.202000852 |
| facet_avail |
Online |
| finc_class_facet |
Physik Chemie und Pharmazie Biologie Technik |
| format |
ElectronicArticle |
| fullrecord |
blob:ai-49-aHR0cDovL2R4LmRvaS5vcmcvMTAuMTAwMi9hZGZtLjIwMjAwMDg1Mg |
| id |
ai-49-aHR0cDovL2R4LmRvaS5vcmcvMTAuMTAwMi9hZGZtLjIwMjAwMDg1Mg |
| institution |
DE-D275 DE-Bn3 DE-Brt1 DE-D161 DE-Gla1 DE-Zi4 DE-15 DE-Pl11 DE-Rs1 DE-105 DE-14 DE-Ch1 DE-L229 |
| imprint |
Wiley, 2020 |
| imprint_str_mv |
Wiley, 2020 |
| issn |
1616-301X 1616-3028 |
| issn_str_mv |
1616-301X 1616-3028 |
| language |
English |
| mega_collection |
Wiley (CrossRef) |
| match_str |
lu2020nitrogendopedti3c2mxenemechanisminvestigationandelectrochemicalanalysis |
| publishDateSort |
2020 |
| publisher |
Wiley |
| recordtype |
ai |
| record_format |
ai |
| series |
Advanced Functional Materials |
| source_id |
49 |
| title |
Nitrogen‐Doped Ti3C2 MXene: Mechanism Investigation and Electrochemical Analysis |
| title_unstemmed |
Nitrogen‐Doped Ti3C2 MXene: Mechanism Investigation and Electrochemical Analysis |
| title_full |
Nitrogen‐Doped Ti3C2 MXene: Mechanism Investigation and Electrochemical Analysis |
| title_fullStr |
Nitrogen‐Doped Ti3C2 MXene: Mechanism Investigation and Electrochemical Analysis |
| title_full_unstemmed |
Nitrogen‐Doped Ti3C2 MXene: Mechanism Investigation and Electrochemical Analysis |
| title_short |
Nitrogen‐Doped Ti3C2 MXene: Mechanism Investigation and Electrochemical Analysis |
| title_sort |
nitrogen‐doped ti<sub>3</sub>c<sub>2</sub> mxene: mechanism investigation and electrochemical analysis |
| topic |
Electrochemistry Condensed Matter Physics Biomaterials Electronic, Optical and Magnetic Materials |
| url |
http://dx.doi.org/10.1002/adfm.202000852 |
| publishDate |
2020 |
| physical |
|
| description |
<jats:title>Abstract</jats:title><jats:p>Nitrogen doping has been proven to be a facile modification strategy to improve the electrochemical performance of 2D MXenes, a group of promising candidates for energy storage applications. However, the underlying mechanisms, especially the positions of nitrogen dopants, and its effect on the electrical properties of MXenes, are still largely unexplored. Herein, a comprehensive study is carried out to disclose the nitrogen doping mechanism in Ti<jats:sub>3</jats:sub>C<jats:sub>2</jats:sub> MXene, by employing theoretical simulation and experimental characterization. Three possible sites are found in Ti<jats:sub>3</jats:sub>C<jats:sub>2</jats:sub>T<jats:italic><jats:sub>x</jats:sub></jats:italic> (T = F, OH, and O) to accommodate the nitrogen dopants: lattice substitution (for carbon), function substitution (for –OH), and surface absorption (on –O). Moreover, electrochemical test results confirm that all the three kinds of nitrogen dopants are favorable for improving the specific capacitance of the Ti<jats:sub>3</jats:sub>C<jats:sub>2</jats:sub> electrode, and the underlying factors are successfully distinguished. By revealing the nitrogen doping mechanisms in Ti<jats:sub>3</jats:sub>C<jats:sub>2</jats:sub> MXene, this work provides theoretical guidelines for modulating the electrochemical properties of MXene materials for energy storage applications.</jats:p> |
| container_issue |
47 |
| container_start_page |
0 |
| container_title |
Advanced Functional Materials |
| container_volume |
30 |
| format_de105 |
Article, E-Article |
| format_de14 |
Article, E-Article |
| format_de15 |
Article, E-Article |
| format_de520 |
Article, E-Article |
| format_de540 |
Article, E-Article |
| format_dech1 |
Article, E-Article |
| format_ded117 |
Article, E-Article |
| format_degla1 |
E-Article |
| format_del152 |
Buch |
| format_del189 |
Article, E-Article |
| format_dezi4 |
Article |
| format_dezwi2 |
Article, E-Article |
| format_finc |
Article, E-Article |
| format_nrw |
Article, E-Article |
| _version_ |
1792348362375168003 |
| geogr_code |
not assigned |
| last_indexed |
2024-03-01T18:09:58.12Z |
| geogr_code_person |
not assigned |
| openURL |
url_ver=Z39.88-2004&ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fvufind.svn.sourceforge.net%3Agenerator&rft.title=Nitrogen%E2%80%90Doped+Ti3C2+MXene%3A+Mechanism+Investigation+and+Electrochemical+Analysis&rft.date=2020-11-01&genre=article&issn=1616-3028&volume=30&issue=47&jtitle=Advanced+Functional+Materials&atitle=Nitrogen%E2%80%90Doped+Ti%3Csub%3E3%3C%2Fsub%3EC%3Csub%3E2%3C%2Fsub%3E+MXene%3A+Mechanism+Investigation+and+Electrochemical+Analysis&aulast=Sun&aufirst=ZhengMing&rft_id=info%3Adoi%2F10.1002%2Fadfm.202000852&rft.language%5B0%5D=eng |
| SOLR | |
| _version_ | 1792348362375168003 |
| author | Lu, Chengjie, Yang, Li, Yan, Bingzhen, Sun, Liangbo, Zhang, Peigen, Zhang, Wei, Sun, ZhengMing |
| author_facet | Lu, Chengjie, Yang, Li, Yan, Bingzhen, Sun, Liangbo, Zhang, Peigen, Zhang, Wei, Sun, ZhengMing, Lu, Chengjie, Yang, Li, Yan, Bingzhen, Sun, Liangbo, Zhang, Peigen, Zhang, Wei, Sun, ZhengMing |
| author_sort | lu, chengjie |
| container_issue | 47 |
| container_start_page | 0 |
| container_title | Advanced Functional Materials |
| container_volume | 30 |
| description | <jats:title>Abstract</jats:title><jats:p>Nitrogen doping has been proven to be a facile modification strategy to improve the electrochemical performance of 2D MXenes, a group of promising candidates for energy storage applications. However, the underlying mechanisms, especially the positions of nitrogen dopants, and its effect on the electrical properties of MXenes, are still largely unexplored. Herein, a comprehensive study is carried out to disclose the nitrogen doping mechanism in Ti<jats:sub>3</jats:sub>C<jats:sub>2</jats:sub> MXene, by employing theoretical simulation and experimental characterization. Three possible sites are found in Ti<jats:sub>3</jats:sub>C<jats:sub>2</jats:sub>T<jats:italic><jats:sub>x</jats:sub></jats:italic> (T = F, OH, and O) to accommodate the nitrogen dopants: lattice substitution (for carbon), function substitution (for –OH), and surface absorption (on –O). Moreover, electrochemical test results confirm that all the three kinds of nitrogen dopants are favorable for improving the specific capacitance of the Ti<jats:sub>3</jats:sub>C<jats:sub>2</jats:sub> electrode, and the underlying factors are successfully distinguished. By revealing the nitrogen doping mechanisms in Ti<jats:sub>3</jats:sub>C<jats:sub>2</jats:sub> MXene, this work provides theoretical guidelines for modulating the electrochemical properties of MXene materials for energy storage applications.</jats:p> |
| doi_str_mv | 10.1002/adfm.202000852 |
| facet_avail | Online |
| finc_class_facet | Physik, Chemie und Pharmazie, Biologie, Technik |
| format | ElectronicArticle |
| format_de105 | Article, E-Article |
| format_de14 | Article, E-Article |
| format_de15 | Article, E-Article |
| format_de520 | Article, E-Article |
| format_de540 | Article, E-Article |
| format_dech1 | Article, E-Article |
| format_ded117 | Article, E-Article |
| format_degla1 | E-Article |
| format_del152 | Buch |
| format_del189 | Article, E-Article |
| format_dezi4 | Article |
| format_dezwi2 | Article, E-Article |
| format_finc | Article, E-Article |
| format_nrw | Article, E-Article |
| geogr_code | not assigned |
| geogr_code_person | not assigned |
| id | ai-49-aHR0cDovL2R4LmRvaS5vcmcvMTAuMTAwMi9hZGZtLjIwMjAwMDg1Mg |
| imprint | Wiley, 2020 |
| imprint_str_mv | Wiley, 2020 |
| institution | DE-D275, DE-Bn3, DE-Brt1, DE-D161, DE-Gla1, DE-Zi4, DE-15, DE-Pl11, DE-Rs1, DE-105, DE-14, DE-Ch1, DE-L229 |
| issn | 1616-301X, 1616-3028 |
| issn_str_mv | 1616-301X, 1616-3028 |
| language | English |
| last_indexed | 2024-03-01T18:09:58.12Z |
| match_str | lu2020nitrogendopedti3c2mxenemechanisminvestigationandelectrochemicalanalysis |
| mega_collection | Wiley (CrossRef) |
| physical | |
| publishDate | 2020 |
| publishDateSort | 2020 |
| publisher | Wiley |
| record_format | ai |
| recordtype | ai |
| series | Advanced Functional Materials |
| source_id | 49 |
| spelling | Lu, Chengjie Yang, Li Yan, Bingzhen Sun, Liangbo Zhang, Peigen Zhang, Wei Sun, ZhengMing 1616-301X 1616-3028 Wiley Electrochemistry Condensed Matter Physics Biomaterials Electronic, Optical and Magnetic Materials http://dx.doi.org/10.1002/adfm.202000852 <jats:title>Abstract</jats:title><jats:p>Nitrogen doping has been proven to be a facile modification strategy to improve the electrochemical performance of 2D MXenes, a group of promising candidates for energy storage applications. However, the underlying mechanisms, especially the positions of nitrogen dopants, and its effect on the electrical properties of MXenes, are still largely unexplored. Herein, a comprehensive study is carried out to disclose the nitrogen doping mechanism in Ti<jats:sub>3</jats:sub>C<jats:sub>2</jats:sub> MXene, by employing theoretical simulation and experimental characterization. Three possible sites are found in Ti<jats:sub>3</jats:sub>C<jats:sub>2</jats:sub>T<jats:italic><jats:sub>x</jats:sub></jats:italic> (T = F, OH, and O) to accommodate the nitrogen dopants: lattice substitution (for carbon), function substitution (for –OH), and surface absorption (on –O). Moreover, electrochemical test results confirm that all the three kinds of nitrogen dopants are favorable for improving the specific capacitance of the Ti<jats:sub>3</jats:sub>C<jats:sub>2</jats:sub> electrode, and the underlying factors are successfully distinguished. By revealing the nitrogen doping mechanisms in Ti<jats:sub>3</jats:sub>C<jats:sub>2</jats:sub> MXene, this work provides theoretical guidelines for modulating the electrochemical properties of MXene materials for energy storage applications.</jats:p> Nitrogen‐Doped Ti<sub>3</sub>C<sub>2</sub> MXene: Mechanism Investigation and Electrochemical Analysis Advanced Functional Materials |
| spellingShingle | Lu, Chengjie, Yang, Li, Yan, Bingzhen, Sun, Liangbo, Zhang, Peigen, Zhang, Wei, Sun, ZhengMing, Advanced Functional Materials, Nitrogen‐Doped Ti3C2 MXene: Mechanism Investigation and Electrochemical Analysis, Electrochemistry, Condensed Matter Physics, Biomaterials, Electronic, Optical and Magnetic Materials |
| title | Nitrogen‐Doped Ti3C2 MXene: Mechanism Investigation and Electrochemical Analysis |
| title_full | Nitrogen‐Doped Ti3C2 MXene: Mechanism Investigation and Electrochemical Analysis |
| title_fullStr | Nitrogen‐Doped Ti3C2 MXene: Mechanism Investigation and Electrochemical Analysis |
| title_full_unstemmed | Nitrogen‐Doped Ti3C2 MXene: Mechanism Investigation and Electrochemical Analysis |
| title_short | Nitrogen‐Doped Ti3C2 MXene: Mechanism Investigation and Electrochemical Analysis |
| title_sort | nitrogen‐doped ti<sub>3</sub>c<sub>2</sub> mxene: mechanism investigation and electrochemical analysis |
| title_unstemmed | Nitrogen‐Doped Ti3C2 MXene: Mechanism Investigation and Electrochemical Analysis |
| topic | Electrochemistry, Condensed Matter Physics, Biomaterials, Electronic, Optical and Magnetic Materials |
| url | http://dx.doi.org/10.1002/adfm.202000852 |