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Transition‐Metal Linkage of Antimony‐Sulfide Chains in [M(dien)2]{Sb18S30[M(dien)]2} (M = Mn, Fe, Co)
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| Zeitschriftentitel: | Zeitschrift für anorganische und allgemeine Chemie |
|---|---|
| Personen und Körperschaften: | , , |
| In: | Zeitschrift für anorganische und allgemeine Chemie, 642, 2016, 23, S. 1402-1407 |
| Format: | E-Article |
| Sprache: | Englisch |
| veröffentlicht: |
Wiley
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| Schlagwörter: |
| author_facet |
Lees, Rachel J. E. Powell, Anthony V. Chippindale, Ann M. Lees, Rachel J. E. Powell, Anthony V. Chippindale, Ann M. |
|---|---|
| author |
Lees, Rachel J. E. Powell, Anthony V. Chippindale, Ann M. |
| spellingShingle |
Lees, Rachel J. E. Powell, Anthony V. Chippindale, Ann M. Zeitschrift für anorganische und allgemeine Chemie Transition‐Metal Linkage of Antimony‐Sulfide Chains in [M(dien)2]{Sb18S30[M(dien)]2} (M = Mn, Fe, Co) Inorganic Chemistry |
| author_sort |
lees, rachel j. e. |
| spelling |
Lees, Rachel J. E. Powell, Anthony V. Chippindale, Ann M. 0044-2313 1521-3749 Wiley Inorganic Chemistry http://dx.doi.org/10.1002/zaac.201600376 <jats:p>Three new isostructural transition‐metal thioantimonates [<jats:italic>M</jats:italic>(dien)<jats:sub>2</jats:sub>]{Sb<jats:sub>18</jats:sub>S<jats:sub>30</jats:sub>[<jats:italic>M</jats:italic>(dien)]<jats:sub>2</jats:sub>} [<jats:italic>M</jats:italic> = Mn (<jats:bold>1</jats:bold>), Fe (<jats:bold>2</jats:bold>), Co (<jats:bold>3</jats:bold>)] were prepared under solvothermal conditions in the presence of diethylenetriamine (dien). The compounds were characterized by single‐crystal X‐ray diffraction, thermogravimetry, elemental analysis, magnetic susceptibility measurements, and UV/Vis reflectance spectroscopy. The materials crystallize in the space group <jats:italic>P</jats:italic><jats:styled-content>1</jats:styled-content> and adopt a structure, in which complex Sb<jats:sub>18</jats:sub>S<jats:sub>30</jats:sub><jats:sup>6–</jats:sup> chains are cross‐linked into layers through transition‐metal‐dimer bridges, [<jats:italic>M</jats:italic><jats:sub>2</jats:sub>S<jats:sub>2</jats:sub>], directly bonded to the thioantimonate layers. The layers contain pores, those in successive layers being aligned to generate a channel structure. Additional [<jats:italic>M</jats:italic>(dien)<jats:sub>2</jats:sub>]<jats:sup>2+</jats:sup> cations are located within these channels in the interlayer space.</jats:p> Transition‐Metal Linkage of Antimony‐Sulfide Chains in [<i>M</i>(dien)<sub>2</sub>]{Sb<sub>18</sub>S<sub>30</sub>[<i>M</i>(dien)]<sub>2</sub>} (<i>M</i> = Mn, Fe, Co) Zeitschrift für anorganische und allgemeine Chemie |
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10.1002/zaac.201600376 |
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Online |
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Chemie und Pharmazie |
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Wiley, 2016 |
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Wiley, 2016 |
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| title |
Transition‐Metal Linkage of Antimony‐Sulfide Chains in [M(dien)2]{Sb18S30[M(dien)]2} (M = Mn, Fe, Co) |
| title_unstemmed |
Transition‐Metal Linkage of Antimony‐Sulfide Chains in [M(dien)2]{Sb18S30[M(dien)]2} (M = Mn, Fe, Co) |
| title_full |
Transition‐Metal Linkage of Antimony‐Sulfide Chains in [M(dien)2]{Sb18S30[M(dien)]2} (M = Mn, Fe, Co) |
| title_fullStr |
Transition‐Metal Linkage of Antimony‐Sulfide Chains in [M(dien)2]{Sb18S30[M(dien)]2} (M = Mn, Fe, Co) |
| title_full_unstemmed |
Transition‐Metal Linkage of Antimony‐Sulfide Chains in [M(dien)2]{Sb18S30[M(dien)]2} (M = Mn, Fe, Co) |
| title_short |
Transition‐Metal Linkage of Antimony‐Sulfide Chains in [M(dien)2]{Sb18S30[M(dien)]2} (M = Mn, Fe, Co) |
| title_sort |
transition‐metal linkage of antimony‐sulfide chains in [<i>m</i>(dien)<sub>2</sub>]{sb<sub>18</sub>s<sub>30</sub>[<i>m</i>(dien)]<sub>2</sub>} (<i>m</i> = mn, fe, co) |
| topic |
Inorganic Chemistry |
| url |
http://dx.doi.org/10.1002/zaac.201600376 |
| publishDate |
2016 |
| physical |
1402-1407 |
| description |
<jats:p>Three new isostructural transition‐metal thioantimonates [<jats:italic>M</jats:italic>(dien)<jats:sub>2</jats:sub>]{Sb<jats:sub>18</jats:sub>S<jats:sub>30</jats:sub>[<jats:italic>M</jats:italic>(dien)]<jats:sub>2</jats:sub>} [<jats:italic>M</jats:italic> = Mn (<jats:bold>1</jats:bold>), Fe (<jats:bold>2</jats:bold>), Co (<jats:bold>3</jats:bold>)] were prepared under solvothermal conditions in the presence of diethylenetriamine (dien). The compounds were characterized by single‐crystal X‐ray diffraction, thermogravimetry, elemental analysis, magnetic susceptibility measurements, and UV/Vis reflectance spectroscopy. The materials crystallize in the space group <jats:italic>P</jats:italic><jats:styled-content>1</jats:styled-content> and adopt a structure, in which complex Sb<jats:sub>18</jats:sub>S<jats:sub>30</jats:sub><jats:sup>6–</jats:sup> chains are cross‐linked into layers through transition‐metal‐dimer bridges, [<jats:italic>M</jats:italic><jats:sub>2</jats:sub>S<jats:sub>2</jats:sub>], directly bonded to the thioantimonate layers. The layers contain pores, those in successive layers being aligned to generate a channel structure. Additional [<jats:italic>M</jats:italic>(dien)<jats:sub>2</jats:sub>]<jats:sup>2+</jats:sup> cations are located within these channels in the interlayer space.</jats:p> |
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| author | Lees, Rachel J. E., Powell, Anthony V., Chippindale, Ann M. |
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| description | <jats:p>Three new isostructural transition‐metal thioantimonates [<jats:italic>M</jats:italic>(dien)<jats:sub>2</jats:sub>]{Sb<jats:sub>18</jats:sub>S<jats:sub>30</jats:sub>[<jats:italic>M</jats:italic>(dien)]<jats:sub>2</jats:sub>} [<jats:italic>M</jats:italic> = Mn (<jats:bold>1</jats:bold>), Fe (<jats:bold>2</jats:bold>), Co (<jats:bold>3</jats:bold>)] were prepared under solvothermal conditions in the presence of diethylenetriamine (dien). The compounds were characterized by single‐crystal X‐ray diffraction, thermogravimetry, elemental analysis, magnetic susceptibility measurements, and UV/Vis reflectance spectroscopy. The materials crystallize in the space group <jats:italic>P</jats:italic><jats:styled-content>1</jats:styled-content> and adopt a structure, in which complex Sb<jats:sub>18</jats:sub>S<jats:sub>30</jats:sub><jats:sup>6–</jats:sup> chains are cross‐linked into layers through transition‐metal‐dimer bridges, [<jats:italic>M</jats:italic><jats:sub>2</jats:sub>S<jats:sub>2</jats:sub>], directly bonded to the thioantimonate layers. The layers contain pores, those in successive layers being aligned to generate a channel structure. Additional [<jats:italic>M</jats:italic>(dien)<jats:sub>2</jats:sub>]<jats:sup>2+</jats:sup> cations are located within these channels in the interlayer space.</jats:p> |
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| institution | DE-Gla1, DE-Zi4, DE-15, DE-Pl11, DE-Rs1, DE-105, DE-14, DE-Ch1, DE-L229, DE-D275, DE-Bn3, DE-Brt1, DE-D161 |
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| spelling | Lees, Rachel J. E. Powell, Anthony V. Chippindale, Ann M. 0044-2313 1521-3749 Wiley Inorganic Chemistry http://dx.doi.org/10.1002/zaac.201600376 <jats:p>Three new isostructural transition‐metal thioantimonates [<jats:italic>M</jats:italic>(dien)<jats:sub>2</jats:sub>]{Sb<jats:sub>18</jats:sub>S<jats:sub>30</jats:sub>[<jats:italic>M</jats:italic>(dien)]<jats:sub>2</jats:sub>} [<jats:italic>M</jats:italic> = Mn (<jats:bold>1</jats:bold>), Fe (<jats:bold>2</jats:bold>), Co (<jats:bold>3</jats:bold>)] were prepared under solvothermal conditions in the presence of diethylenetriamine (dien). The compounds were characterized by single‐crystal X‐ray diffraction, thermogravimetry, elemental analysis, magnetic susceptibility measurements, and UV/Vis reflectance spectroscopy. The materials crystallize in the space group <jats:italic>P</jats:italic><jats:styled-content>1</jats:styled-content> and adopt a structure, in which complex Sb<jats:sub>18</jats:sub>S<jats:sub>30</jats:sub><jats:sup>6–</jats:sup> chains are cross‐linked into layers through transition‐metal‐dimer bridges, [<jats:italic>M</jats:italic><jats:sub>2</jats:sub>S<jats:sub>2</jats:sub>], directly bonded to the thioantimonate layers. The layers contain pores, those in successive layers being aligned to generate a channel structure. Additional [<jats:italic>M</jats:italic>(dien)<jats:sub>2</jats:sub>]<jats:sup>2+</jats:sup> cations are located within these channels in the interlayer space.</jats:p> Transition‐Metal Linkage of Antimony‐Sulfide Chains in [<i>M</i>(dien)<sub>2</sub>]{Sb<sub>18</sub>S<sub>30</sub>[<i>M</i>(dien)]<sub>2</sub>} (<i>M</i> = Mn, Fe, Co) Zeitschrift für anorganische und allgemeine Chemie |
| spellingShingle | Lees, Rachel J. E., Powell, Anthony V., Chippindale, Ann M., Zeitschrift für anorganische und allgemeine Chemie, Transition‐Metal Linkage of Antimony‐Sulfide Chains in [M(dien)2]{Sb18S30[M(dien)]2} (M = Mn, Fe, Co), Inorganic Chemistry |
| title | Transition‐Metal Linkage of Antimony‐Sulfide Chains in [M(dien)2]{Sb18S30[M(dien)]2} (M = Mn, Fe, Co) |
| title_full | Transition‐Metal Linkage of Antimony‐Sulfide Chains in [M(dien)2]{Sb18S30[M(dien)]2} (M = Mn, Fe, Co) |
| title_fullStr | Transition‐Metal Linkage of Antimony‐Sulfide Chains in [M(dien)2]{Sb18S30[M(dien)]2} (M = Mn, Fe, Co) |
| title_full_unstemmed | Transition‐Metal Linkage of Antimony‐Sulfide Chains in [M(dien)2]{Sb18S30[M(dien)]2} (M = Mn, Fe, Co) |
| title_short | Transition‐Metal Linkage of Antimony‐Sulfide Chains in [M(dien)2]{Sb18S30[M(dien)]2} (M = Mn, Fe, Co) |
| title_sort | transition‐metal linkage of antimony‐sulfide chains in [<i>m</i>(dien)<sub>2</sub>]{sb<sub>18</sub>s<sub>30</sub>[<i>m</i>(dien)]<sub>2</sub>} (<i>m</i> = mn, fe, co) |
| title_unstemmed | Transition‐Metal Linkage of Antimony‐Sulfide Chains in [M(dien)2]{Sb18S30[M(dien)]2} (M = Mn, Fe, Co) |
| topic | Inorganic Chemistry |
| url | http://dx.doi.org/10.1002/zaac.201600376 |