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Pyridine vs. Bipyridine Coordination in PtCl2 Complexes of 4‐tButyl‐4'‐(4‐pyridinyl)‐2, 2'‐bipyridine
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| Zeitschriftentitel: | Zeitschrift für anorganische und allgemeine Chemie |
|---|---|
| Personen und Körperschaften: | , , |
| In: | Zeitschrift für anorganische und allgemeine Chemie, 639, 2013, 14, S. 2565-2574 |
| Format: | E-Article |
| Sprache: | Englisch |
| veröffentlicht: |
Wiley
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| Schlagwörter: |
| author_facet |
Rank, Matthias Zabel, Manfred Winter, Rainer F. Rank, Matthias Zabel, Manfred Winter, Rainer F. |
|---|---|
| author |
Rank, Matthias Zabel, Manfred Winter, Rainer F. |
| spellingShingle |
Rank, Matthias Zabel, Manfred Winter, Rainer F. Zeitschrift für anorganische und allgemeine Chemie Pyridine vs. Bipyridine Coordination in PtCl2 Complexes of 4‐tButyl‐4'‐(4‐pyridinyl)‐2, 2'‐bipyridine Inorganic Chemistry |
| author_sort |
rank, matthias |
| spelling |
Rank, Matthias Zabel, Manfred Winter, Rainer F. 0044-2313 1521-3749 Wiley Inorganic Chemistry http://dx.doi.org/10.1002/zaac.201300139 <jats:title>Abstract</jats:title><jats:p>The reaction of the new terpyridine ligand 4‐<jats:sup><jats:italic>t</jats:italic></jats:sup>butyl‐4'‐(4‐pyridinyl)‐2, 2'‐bipyridine <jats:bold>L </jats:bold>with various sources of “PtCl<jats:sub>2</jats:sub>” selectively yields either <jats:italic>trans‐</jats:italic>[PtCl<jats:sub>2</jats:sub>(<jats:bold>L</jats:bold>)<jats:sub>2</jats:sub>] (<jats:bold>1</jats:bold>) with <jats:bold>L </jats:bold>bonded in a monodentate fashion via its pendant 4‐pyridyl ring or <jats:italic>cis</jats:italic>‐[PtCl<jats:sub>2</jats:sub>(<jats:bold>L</jats:bold>)] (<jats:bold>2</jats:bold>), where <jats:bold>L </jats:bold>coordinates in a bidentate fashion through its 2, 2'‐bipyridine subunit. The molecular structures of <jats:bold>L</jats:bold> and of complex <jats:bold>1 </jats:bold>were determined by X‐ray crystallography and exhibit intra‐ and intermolecular hydrogen bonding. We have also converted the dichloro complex <jats:bold>2</jats:bold> into the bis(coumarin thiolate) complex <jats:bold>3</jats:bold>. Owing to their free imine coordination sites, complexes <jats:bold>1–3 </jats:bold>constitute interesting building blocks for multimetal structures in a “complexes as ligands” approach. The reductive behaviour of <jats:bold>L</jats:bold> and of complexes <jats:bold>1–3</jats:bold> has been investigated by cyclic and square wave voltammetry.</jats:p> Pyridine vs. Bipyridine Coordination in PtCl<sub>2</sub> Complexes of 4‐<i><sup>t</sup></i>Butyl‐4'‐(4‐pyridinyl)‐2, 2'‐bipyridine Zeitschrift für anorganische und allgemeine Chemie |
| doi_str_mv |
10.1002/zaac.201300139 |
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Online |
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Chemie und Pharmazie |
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DE-D275 DE-Bn3 DE-Brt1 DE-D161 DE-Gla1 DE-Zi4 DE-15 DE-Pl11 DE-Rs1 DE-105 DE-14 DE-Ch1 DE-L229 |
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Wiley, 2013 |
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Wiley, 2013 |
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0044-2313 1521-3749 |
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| title |
Pyridine vs. Bipyridine Coordination in PtCl2 Complexes of 4‐tButyl‐4'‐(4‐pyridinyl)‐2, 2'‐bipyridine |
| title_unstemmed |
Pyridine vs. Bipyridine Coordination in PtCl2 Complexes of 4‐tButyl‐4'‐(4‐pyridinyl)‐2, 2'‐bipyridine |
| title_full |
Pyridine vs. Bipyridine Coordination in PtCl2 Complexes of 4‐tButyl‐4'‐(4‐pyridinyl)‐2, 2'‐bipyridine |
| title_fullStr |
Pyridine vs. Bipyridine Coordination in PtCl2 Complexes of 4‐tButyl‐4'‐(4‐pyridinyl)‐2, 2'‐bipyridine |
| title_full_unstemmed |
Pyridine vs. Bipyridine Coordination in PtCl2 Complexes of 4‐tButyl‐4'‐(4‐pyridinyl)‐2, 2'‐bipyridine |
| title_short |
Pyridine vs. Bipyridine Coordination in PtCl2 Complexes of 4‐tButyl‐4'‐(4‐pyridinyl)‐2, 2'‐bipyridine |
| title_sort |
pyridine vs. bipyridine coordination in ptcl<sub>2</sub> complexes of 4‐<i><sup>t</sup></i>butyl‐4'‐(4‐pyridinyl)‐2, 2'‐bipyridine |
| topic |
Inorganic Chemistry |
| url |
http://dx.doi.org/10.1002/zaac.201300139 |
| publishDate |
2013 |
| physical |
2565-2574 |
| description |
<jats:title>Abstract</jats:title><jats:p>The reaction of the new terpyridine ligand 4‐<jats:sup><jats:italic>t</jats:italic></jats:sup>butyl‐4'‐(4‐pyridinyl)‐2, 2'‐bipyridine <jats:bold>L </jats:bold>with various sources of “PtCl<jats:sub>2</jats:sub>” selectively yields either <jats:italic>trans‐</jats:italic>[PtCl<jats:sub>2</jats:sub>(<jats:bold>L</jats:bold>)<jats:sub>2</jats:sub>] (<jats:bold>1</jats:bold>) with <jats:bold>L </jats:bold>bonded in a monodentate fashion via its pendant 4‐pyridyl ring or <jats:italic>cis</jats:italic>‐[PtCl<jats:sub>2</jats:sub>(<jats:bold>L</jats:bold>)] (<jats:bold>2</jats:bold>), where <jats:bold>L </jats:bold>coordinates in a bidentate fashion through its 2, 2'‐bipyridine subunit. The molecular structures of <jats:bold>L</jats:bold> and of complex <jats:bold>1 </jats:bold>were determined by X‐ray crystallography and exhibit intra‐ and intermolecular hydrogen bonding. We have also converted the dichloro complex <jats:bold>2</jats:bold> into the bis(coumarin thiolate) complex <jats:bold>3</jats:bold>. Owing to their free imine coordination sites, complexes <jats:bold>1–3 </jats:bold>constitute interesting building blocks for multimetal structures in a “complexes as ligands” approach. The reductive behaviour of <jats:bold>L</jats:bold> and of complexes <jats:bold>1–3</jats:bold> has been investigated by cyclic and square wave voltammetry.</jats:p> |
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| author | Rank, Matthias, Zabel, Manfred, Winter, Rainer F. |
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| description | <jats:title>Abstract</jats:title><jats:p>The reaction of the new terpyridine ligand 4‐<jats:sup><jats:italic>t</jats:italic></jats:sup>butyl‐4'‐(4‐pyridinyl)‐2, 2'‐bipyridine <jats:bold>L </jats:bold>with various sources of “PtCl<jats:sub>2</jats:sub>” selectively yields either <jats:italic>trans‐</jats:italic>[PtCl<jats:sub>2</jats:sub>(<jats:bold>L</jats:bold>)<jats:sub>2</jats:sub>] (<jats:bold>1</jats:bold>) with <jats:bold>L </jats:bold>bonded in a monodentate fashion via its pendant 4‐pyridyl ring or <jats:italic>cis</jats:italic>‐[PtCl<jats:sub>2</jats:sub>(<jats:bold>L</jats:bold>)] (<jats:bold>2</jats:bold>), where <jats:bold>L </jats:bold>coordinates in a bidentate fashion through its 2, 2'‐bipyridine subunit. The molecular structures of <jats:bold>L</jats:bold> and of complex <jats:bold>1 </jats:bold>were determined by X‐ray crystallography and exhibit intra‐ and intermolecular hydrogen bonding. We have also converted the dichloro complex <jats:bold>2</jats:bold> into the bis(coumarin thiolate) complex <jats:bold>3</jats:bold>. Owing to their free imine coordination sites, complexes <jats:bold>1–3 </jats:bold>constitute interesting building blocks for multimetal structures in a “complexes as ligands” approach. The reductive behaviour of <jats:bold>L</jats:bold> and of complexes <jats:bold>1–3</jats:bold> has been investigated by cyclic and square wave voltammetry.</jats:p> |
| doi_str_mv | 10.1002/zaac.201300139 |
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| imprint | Wiley, 2013 |
| imprint_str_mv | Wiley, 2013 |
| institution | DE-D275, DE-Bn3, DE-Brt1, DE-D161, DE-Gla1, DE-Zi4, DE-15, DE-Pl11, DE-Rs1, DE-105, DE-14, DE-Ch1, DE-L229 |
| issn | 0044-2313, 1521-3749 |
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| language | English |
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| physical | 2565-2574 |
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| series | Zeitschrift für anorganische und allgemeine Chemie |
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| spelling | Rank, Matthias Zabel, Manfred Winter, Rainer F. 0044-2313 1521-3749 Wiley Inorganic Chemistry http://dx.doi.org/10.1002/zaac.201300139 <jats:title>Abstract</jats:title><jats:p>The reaction of the new terpyridine ligand 4‐<jats:sup><jats:italic>t</jats:italic></jats:sup>butyl‐4'‐(4‐pyridinyl)‐2, 2'‐bipyridine <jats:bold>L </jats:bold>with various sources of “PtCl<jats:sub>2</jats:sub>” selectively yields either <jats:italic>trans‐</jats:italic>[PtCl<jats:sub>2</jats:sub>(<jats:bold>L</jats:bold>)<jats:sub>2</jats:sub>] (<jats:bold>1</jats:bold>) with <jats:bold>L </jats:bold>bonded in a monodentate fashion via its pendant 4‐pyridyl ring or <jats:italic>cis</jats:italic>‐[PtCl<jats:sub>2</jats:sub>(<jats:bold>L</jats:bold>)] (<jats:bold>2</jats:bold>), where <jats:bold>L </jats:bold>coordinates in a bidentate fashion through its 2, 2'‐bipyridine subunit. The molecular structures of <jats:bold>L</jats:bold> and of complex <jats:bold>1 </jats:bold>were determined by X‐ray crystallography and exhibit intra‐ and intermolecular hydrogen bonding. We have also converted the dichloro complex <jats:bold>2</jats:bold> into the bis(coumarin thiolate) complex <jats:bold>3</jats:bold>. Owing to their free imine coordination sites, complexes <jats:bold>1–3 </jats:bold>constitute interesting building blocks for multimetal structures in a “complexes as ligands” approach. The reductive behaviour of <jats:bold>L</jats:bold> and of complexes <jats:bold>1–3</jats:bold> has been investigated by cyclic and square wave voltammetry.</jats:p> Pyridine vs. Bipyridine Coordination in PtCl<sub>2</sub> Complexes of 4‐<i><sup>t</sup></i>Butyl‐4'‐(4‐pyridinyl)‐2, 2'‐bipyridine Zeitschrift für anorganische und allgemeine Chemie |
| spellingShingle | Rank, Matthias, Zabel, Manfred, Winter, Rainer F., Zeitschrift für anorganische und allgemeine Chemie, Pyridine vs. Bipyridine Coordination in PtCl2 Complexes of 4‐tButyl‐4'‐(4‐pyridinyl)‐2, 2'‐bipyridine, Inorganic Chemistry |
| title | Pyridine vs. Bipyridine Coordination in PtCl2 Complexes of 4‐tButyl‐4'‐(4‐pyridinyl)‐2, 2'‐bipyridine |
| title_full | Pyridine vs. Bipyridine Coordination in PtCl2 Complexes of 4‐tButyl‐4'‐(4‐pyridinyl)‐2, 2'‐bipyridine |
| title_fullStr | Pyridine vs. Bipyridine Coordination in PtCl2 Complexes of 4‐tButyl‐4'‐(4‐pyridinyl)‐2, 2'‐bipyridine |
| title_full_unstemmed | Pyridine vs. Bipyridine Coordination in PtCl2 Complexes of 4‐tButyl‐4'‐(4‐pyridinyl)‐2, 2'‐bipyridine |
| title_short | Pyridine vs. Bipyridine Coordination in PtCl2 Complexes of 4‐tButyl‐4'‐(4‐pyridinyl)‐2, 2'‐bipyridine |
| title_sort | pyridine vs. bipyridine coordination in ptcl<sub>2</sub> complexes of 4‐<i><sup>t</sup></i>butyl‐4'‐(4‐pyridinyl)‐2, 2'‐bipyridine |
| title_unstemmed | Pyridine vs. Bipyridine Coordination in PtCl2 Complexes of 4‐tButyl‐4'‐(4‐pyridinyl)‐2, 2'‐bipyridine |
| topic | Inorganic Chemistry |
| url | http://dx.doi.org/10.1002/zaac.201300139 |