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Preparation and crystal structure of a new acentric caesium iron hydrogen phosphate, Cs3Fe3H15(PO4)9
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| Zeitschriftentitel: | Zeitschrift für anorganische und allgemeine Chemie |
|---|---|
| Personen und Körperschaften: | , , , , |
| In: | Zeitschrift für anorganische und allgemeine Chemie, 622, 1996, 11, S. 1920-1926 |
| Format: | E-Article |
| Sprache: | Englisch |
| veröffentlicht: |
Wiley
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| Schlagwörter: |
| author_facet |
Anisimova, N. Schülke, U. Bork, M. Hoppe, R. Serafin, M. Anisimova, N. Schülke, U. Bork, M. Hoppe, R. Serafin, M. |
|---|---|
| author |
Anisimova, N. Schülke, U. Bork, M. Hoppe, R. Serafin, M. |
| spellingShingle |
Anisimova, N. Schülke, U. Bork, M. Hoppe, R. Serafin, M. Zeitschrift für anorganische und allgemeine Chemie Preparation and crystal structure of a new acentric caesium iron hydrogen phosphate, Cs3Fe3H15(PO4)9 Inorganic Chemistry |
| author_sort |
anisimova, n. |
| spelling |
Anisimova, N. Schülke, U. Bork, M. Hoppe, R. Serafin, M. 0044-2313 1521-3749 Wiley Inorganic Chemistry http://dx.doi.org/10.1002/zaac.19966221118 <jats:title>Abstract</jats:title><jats:p>Single crystals of caesium iron hydrogen phosphate, Cs<jats:sub>3</jats:sub>Fe<jats:sub>3</jats:sub>H<jats:sub>15</jats:sub>(PO<jats:sub>4</jats:sub>)<jats:sub>9</jats:sub>, <jats:bold>2</jats:bold>, were prepared hydrothermally by heating caesium iron dihydrogenphosphate, CsFe(H<jats:sub>2</jats:sub>PO<jats:sub>4</jats:sub>)<jats:sub>4</jats:sub>, <jats:bold>1</jats:bold>, with a small amount of water. <jats:bold>2</jats:bold> crystallizes orthorhombic, space group Pna2<jats:sub>1</jats:sub> (No. 33 Int. Tab.) with Z = 4 and a = 2718(1), b = 908.1(3), c = 1280.8(4) pm.</jats:p><jats:p>The crystal structure was solved by using 4734 unique reflections I > 2σ(I) with a final wR2 value of 0.0801 (SHELXL‐93).</jats:p><jats:p>The main feature of the crystal structure are channels formed by combined PO<jats:sub>4</jats:sub>‐tetrahedra and FeO<jats:sub>6</jats:sub>‐octahedra along the [001] direction. Cs<jats:sup>+</jats:sup> is placed inside of the channels. Effective Coordination Numbers (ECoN), Mean Fictive Ionic Radii (MEFIR), Charge Distribution (CHARDI) and the Madelung Part of Lattice Energy (MAPLE) are calculated for the title compound.</jats:p> Preparation and crystal structure of a new acentric caesium iron hydrogen phosphate, Cs<sub>3</sub>Fe<sub>3</sub>H<sub>15</sub>(PO<sub>4</sub>)<sub>9</sub> Zeitschrift für anorganische und allgemeine Chemie |
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10.1002/zaac.19966221118 |
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Online |
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Chemie und Pharmazie |
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Wiley, 1996 |
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Wiley, 1996 |
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1521-3749 0044-2313 |
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1996 |
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Wiley |
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Zeitschrift für anorganische und allgemeine Chemie |
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49 |
| title |
Preparation and crystal structure of a new acentric caesium iron hydrogen phosphate, Cs3Fe3H15(PO4)9 |
| title_unstemmed |
Preparation and crystal structure of a new acentric caesium iron hydrogen phosphate, Cs3Fe3H15(PO4)9 |
| title_full |
Preparation and crystal structure of a new acentric caesium iron hydrogen phosphate, Cs3Fe3H15(PO4)9 |
| title_fullStr |
Preparation and crystal structure of a new acentric caesium iron hydrogen phosphate, Cs3Fe3H15(PO4)9 |
| title_full_unstemmed |
Preparation and crystal structure of a new acentric caesium iron hydrogen phosphate, Cs3Fe3H15(PO4)9 |
| title_short |
Preparation and crystal structure of a new acentric caesium iron hydrogen phosphate, Cs3Fe3H15(PO4)9 |
| title_sort |
preparation and crystal structure of a new acentric caesium iron hydrogen phosphate, cs<sub>3</sub>fe<sub>3</sub>h<sub>15</sub>(po<sub>4</sub>)<sub>9</sub> |
| topic |
Inorganic Chemistry |
| url |
http://dx.doi.org/10.1002/zaac.19966221118 |
| publishDate |
1996 |
| physical |
1920-1926 |
| description |
<jats:title>Abstract</jats:title><jats:p>Single crystals of caesium iron hydrogen phosphate, Cs<jats:sub>3</jats:sub>Fe<jats:sub>3</jats:sub>H<jats:sub>15</jats:sub>(PO<jats:sub>4</jats:sub>)<jats:sub>9</jats:sub>, <jats:bold>2</jats:bold>, were prepared hydrothermally by heating caesium iron dihydrogenphosphate, CsFe(H<jats:sub>2</jats:sub>PO<jats:sub>4</jats:sub>)<jats:sub>4</jats:sub>, <jats:bold>1</jats:bold>, with a small amount of water. <jats:bold>2</jats:bold> crystallizes orthorhombic, space group Pna2<jats:sub>1</jats:sub> (No. 33 Int. Tab.) with Z = 4 and a = 2718(1), b = 908.1(3), c = 1280.8(4) pm.</jats:p><jats:p>The crystal structure was solved by using 4734 unique reflections I > 2σ(I) with a final wR2 value of 0.0801 (SHELXL‐93).</jats:p><jats:p>The main feature of the crystal structure are channels formed by combined PO<jats:sub>4</jats:sub>‐tetrahedra and FeO<jats:sub>6</jats:sub>‐octahedra along the [001] direction. Cs<jats:sup>+</jats:sup> is placed inside of the channels. Effective Coordination Numbers (ECoN), Mean Fictive Ionic Radii (MEFIR), Charge Distribution (CHARDI) and the Madelung Part of Lattice Energy (MAPLE) are calculated for the title compound.</jats:p> |
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url_ver=Z39.88-2004&ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fvufind.svn.sourceforge.net%3Agenerator&rft.title=Preparation+and+crystal+structure+of+a+new+acentric+caesium+iron+hydrogen+phosphate%2C+Cs3Fe3H15%28PO4%299&rft.date=1996-11-01&genre=article&issn=1521-3749&volume=622&issue=11&spage=1920&epage=1926&pages=1920-1926&jtitle=Zeitschrift+f%C3%BCr+anorganische+und+allgemeine+Chemie&atitle=Preparation+and+crystal+structure+of+a+new+acentric+caesium+iron+hydrogen+phosphate%2C+Cs%3Csub%3E3%3C%2Fsub%3EFe%3Csub%3E3%3C%2Fsub%3EH%3Csub%3E15%3C%2Fsub%3E%28PO%3Csub%3E4%3C%2Fsub%3E%29%3Csub%3E9%3C%2Fsub%3E&aulast=Serafin&aufirst=M.&rft_id=info%3Adoi%2F10.1002%2Fzaac.19966221118&rft.language%5B0%5D=eng |
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| author | Anisimova, N., Schülke, U., Bork, M., Hoppe, R., Serafin, M. |
| author_facet | Anisimova, N., Schülke, U., Bork, M., Hoppe, R., Serafin, M., Anisimova, N., Schülke, U., Bork, M., Hoppe, R., Serafin, M. |
| author_sort | anisimova, n. |
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| description | <jats:title>Abstract</jats:title><jats:p>Single crystals of caesium iron hydrogen phosphate, Cs<jats:sub>3</jats:sub>Fe<jats:sub>3</jats:sub>H<jats:sub>15</jats:sub>(PO<jats:sub>4</jats:sub>)<jats:sub>9</jats:sub>, <jats:bold>2</jats:bold>, were prepared hydrothermally by heating caesium iron dihydrogenphosphate, CsFe(H<jats:sub>2</jats:sub>PO<jats:sub>4</jats:sub>)<jats:sub>4</jats:sub>, <jats:bold>1</jats:bold>, with a small amount of water. <jats:bold>2</jats:bold> crystallizes orthorhombic, space group Pna2<jats:sub>1</jats:sub> (No. 33 Int. Tab.) with Z = 4 and a = 2718(1), b = 908.1(3), c = 1280.8(4) pm.</jats:p><jats:p>The crystal structure was solved by using 4734 unique reflections I > 2σ(I) with a final wR2 value of 0.0801 (SHELXL‐93).</jats:p><jats:p>The main feature of the crystal structure are channels formed by combined PO<jats:sub>4</jats:sub>‐tetrahedra and FeO<jats:sub>6</jats:sub>‐octahedra along the [001] direction. Cs<jats:sup>+</jats:sup> is placed inside of the channels. Effective Coordination Numbers (ECoN), Mean Fictive Ionic Radii (MEFIR), Charge Distribution (CHARDI) and the Madelung Part of Lattice Energy (MAPLE) are calculated for the title compound.</jats:p> |
| doi_str_mv | 10.1002/zaac.19966221118 |
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| finc_class_facet | Chemie und Pharmazie |
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| id | ai-49-aHR0cDovL2R4LmRvaS5vcmcvMTAuMTAwMi96YWFjLjE5OTY2MjIxMTE4 |
| imprint | Wiley, 1996 |
| imprint_str_mv | Wiley, 1996 |
| institution | DE-Gla1, DE-Zi4, DE-15, DE-Pl11, DE-Rs1, DE-105, DE-14, DE-Ch1, DE-L229, DE-D275, DE-Bn3, DE-Brt1, DE-D161 |
| issn | 1521-3749, 0044-2313 |
| issn_str_mv | 1521-3749, 0044-2313 |
| language | English |
| last_indexed | 2024-03-01T15:10:13.51Z |
| match_str | anisimova1996preparationandcrystalstructureofanewacentriccaesiumironhydrogenphosphatecs3fe3h15po49 |
| mega_collection | Wiley (CrossRef) |
| physical | 1920-1926 |
| publishDate | 1996 |
| publishDateSort | 1996 |
| publisher | Wiley |
| record_format | ai |
| recordtype | ai |
| series | Zeitschrift für anorganische und allgemeine Chemie |
| source_id | 49 |
| spelling | Anisimova, N. Schülke, U. Bork, M. Hoppe, R. Serafin, M. 0044-2313 1521-3749 Wiley Inorganic Chemistry http://dx.doi.org/10.1002/zaac.19966221118 <jats:title>Abstract</jats:title><jats:p>Single crystals of caesium iron hydrogen phosphate, Cs<jats:sub>3</jats:sub>Fe<jats:sub>3</jats:sub>H<jats:sub>15</jats:sub>(PO<jats:sub>4</jats:sub>)<jats:sub>9</jats:sub>, <jats:bold>2</jats:bold>, were prepared hydrothermally by heating caesium iron dihydrogenphosphate, CsFe(H<jats:sub>2</jats:sub>PO<jats:sub>4</jats:sub>)<jats:sub>4</jats:sub>, <jats:bold>1</jats:bold>, with a small amount of water. <jats:bold>2</jats:bold> crystallizes orthorhombic, space group Pna2<jats:sub>1</jats:sub> (No. 33 Int. Tab.) with Z = 4 and a = 2718(1), b = 908.1(3), c = 1280.8(4) pm.</jats:p><jats:p>The crystal structure was solved by using 4734 unique reflections I > 2σ(I) with a final wR2 value of 0.0801 (SHELXL‐93).</jats:p><jats:p>The main feature of the crystal structure are channels formed by combined PO<jats:sub>4</jats:sub>‐tetrahedra and FeO<jats:sub>6</jats:sub>‐octahedra along the [001] direction. Cs<jats:sup>+</jats:sup> is placed inside of the channels. Effective Coordination Numbers (ECoN), Mean Fictive Ionic Radii (MEFIR), Charge Distribution (CHARDI) and the Madelung Part of Lattice Energy (MAPLE) are calculated for the title compound.</jats:p> Preparation and crystal structure of a new acentric caesium iron hydrogen phosphate, Cs<sub>3</sub>Fe<sub>3</sub>H<sub>15</sub>(PO<sub>4</sub>)<sub>9</sub> Zeitschrift für anorganische und allgemeine Chemie |
| spellingShingle | Anisimova, N., Schülke, U., Bork, M., Hoppe, R., Serafin, M., Zeitschrift für anorganische und allgemeine Chemie, Preparation and crystal structure of a new acentric caesium iron hydrogen phosphate, Cs3Fe3H15(PO4)9, Inorganic Chemistry |
| title | Preparation and crystal structure of a new acentric caesium iron hydrogen phosphate, Cs3Fe3H15(PO4)9 |
| title_full | Preparation and crystal structure of a new acentric caesium iron hydrogen phosphate, Cs3Fe3H15(PO4)9 |
| title_fullStr | Preparation and crystal structure of a new acentric caesium iron hydrogen phosphate, Cs3Fe3H15(PO4)9 |
| title_full_unstemmed | Preparation and crystal structure of a new acentric caesium iron hydrogen phosphate, Cs3Fe3H15(PO4)9 |
| title_short | Preparation and crystal structure of a new acentric caesium iron hydrogen phosphate, Cs3Fe3H15(PO4)9 |
| title_sort | preparation and crystal structure of a new acentric caesium iron hydrogen phosphate, cs<sub>3</sub>fe<sub>3</sub>h<sub>15</sub>(po<sub>4</sub>)<sub>9</sub> |
| title_unstemmed | Preparation and crystal structure of a new acentric caesium iron hydrogen phosphate, Cs3Fe3H15(PO4)9 |
| topic | Inorganic Chemistry |
| url | http://dx.doi.org/10.1002/zaac.19966221118 |