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Intermolecular forces involving the water molecules in lithium sulfate monohydrate
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Zeitschriftentitel: | The Journal of Chemical Physics |
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Personen und Körperschaften: | , |
In: | The Journal of Chemical Physics, 64, 1976, 10, S. 3961-3970 |
Format: | E-Article |
Sprache: | Englisch |
veröffentlicht: |
AIP Publishing
|
Schlagwörter: |
author_facet |
Hayward, H. Preston Schiffer, Jerome Hayward, H. Preston Schiffer, Jerome |
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author |
Hayward, H. Preston Schiffer, Jerome |
spellingShingle |
Hayward, H. Preston Schiffer, Jerome The Journal of Chemical Physics Intermolecular forces involving the water molecules in lithium sulfate monohydrate Physical and Theoretical Chemistry General Physics and Astronomy |
author_sort |
hayward, h. preston |
spelling |
Hayward, H. Preston Schiffer, Jerome 0021-9606 1089-7690 AIP Publishing Physical and Theoretical Chemistry General Physics and Astronomy http://dx.doi.org/10.1063/1.432027 <jats:p>A study of the low-temperature infrared spectra of varyingly deuterated mulls of lithium sulfate monohydrate has afforded information as to the nature of vibrations of water molecules causing infrared absorptions. Using intra- and intermolecular force constants, obtained from the data of doublet spectra, spectra of intermolecularly coupled species were predicted and compared with experiment. The agreement between calculated and observed spectra is good, but not perfect. This indicates that nonneighbor interactions are weak but significant in determining the nature of the stretching modes involving water molecules in Li2SO4⋅H2O. Furthermore, it is shown that the intermolecular interactions involving water molecules are mostly dipolar in origin.</jats:p> Intermolecular forces involving the water molecules in lithium sulfate monohydrate The Journal of Chemical Physics |
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10.1063/1.432027 |
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Chemie und Pharmazie Physik |
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AIP Publishing, 1976 |
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1976 |
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AIP Publishing |
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The Journal of Chemical Physics |
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49 |
title |
Intermolecular forces involving the water molecules in lithium sulfate monohydrate |
title_unstemmed |
Intermolecular forces involving the water molecules in lithium sulfate monohydrate |
title_full |
Intermolecular forces involving the water molecules in lithium sulfate monohydrate |
title_fullStr |
Intermolecular forces involving the water molecules in lithium sulfate monohydrate |
title_full_unstemmed |
Intermolecular forces involving the water molecules in lithium sulfate monohydrate |
title_short |
Intermolecular forces involving the water molecules in lithium sulfate monohydrate |
title_sort |
intermolecular forces involving the water molecules in lithium sulfate monohydrate |
topic |
Physical and Theoretical Chemistry General Physics and Astronomy |
url |
http://dx.doi.org/10.1063/1.432027 |
publishDate |
1976 |
physical |
3961-3970 |
description |
<jats:p>A study of the low-temperature infrared spectra of varyingly deuterated mulls of lithium sulfate monohydrate has afforded information as to the nature of vibrations of water molecules causing infrared absorptions. Using intra- and intermolecular force constants, obtained from the data of doublet spectra, spectra of intermolecularly coupled species were predicted and compared with experiment. The agreement between calculated and observed spectra is good, but not perfect. This indicates that nonneighbor interactions are weak but significant in determining the nature of the stretching modes involving water molecules in Li2SO4⋅H2O. Furthermore, it is shown that the intermolecular interactions involving water molecules are mostly dipolar in origin.</jats:p> |
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author | Hayward, H. Preston, Schiffer, Jerome |
author_facet | Hayward, H. Preston, Schiffer, Jerome, Hayward, H. Preston, Schiffer, Jerome |
author_sort | hayward, h. preston |
container_issue | 10 |
container_start_page | 3961 |
container_title | The Journal of Chemical Physics |
container_volume | 64 |
description | <jats:p>A study of the low-temperature infrared spectra of varyingly deuterated mulls of lithium sulfate monohydrate has afforded information as to the nature of vibrations of water molecules causing infrared absorptions. Using intra- and intermolecular force constants, obtained from the data of doublet spectra, spectra of intermolecularly coupled species were predicted and compared with experiment. The agreement between calculated and observed spectra is good, but not perfect. This indicates that nonneighbor interactions are weak but significant in determining the nature of the stretching modes involving water molecules in Li2SO4⋅H2O. Furthermore, it is shown that the intermolecular interactions involving water molecules are mostly dipolar in origin.</jats:p> |
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imprint | AIP Publishing, 1976 |
imprint_str_mv | AIP Publishing, 1976 |
institution | DE-Ch1, DE-L229, DE-D275, DE-Bn3, DE-Brt1, DE-D161, DE-Zi4, DE-Gla1, DE-15, DE-Pl11, DE-Rs1, DE-14, DE-105 |
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spelling | Hayward, H. Preston Schiffer, Jerome 0021-9606 1089-7690 AIP Publishing Physical and Theoretical Chemistry General Physics and Astronomy http://dx.doi.org/10.1063/1.432027 <jats:p>A study of the low-temperature infrared spectra of varyingly deuterated mulls of lithium sulfate monohydrate has afforded information as to the nature of vibrations of water molecules causing infrared absorptions. Using intra- and intermolecular force constants, obtained from the data of doublet spectra, spectra of intermolecularly coupled species were predicted and compared with experiment. The agreement between calculated and observed spectra is good, but not perfect. This indicates that nonneighbor interactions are weak but significant in determining the nature of the stretching modes involving water molecules in Li2SO4⋅H2O. Furthermore, it is shown that the intermolecular interactions involving water molecules are mostly dipolar in origin.</jats:p> Intermolecular forces involving the water molecules in lithium sulfate monohydrate The Journal of Chemical Physics |
spellingShingle | Hayward, H. Preston, Schiffer, Jerome, The Journal of Chemical Physics, Intermolecular forces involving the water molecules in lithium sulfate monohydrate, Physical and Theoretical Chemistry, General Physics and Astronomy |
title | Intermolecular forces involving the water molecules in lithium sulfate monohydrate |
title_full | Intermolecular forces involving the water molecules in lithium sulfate monohydrate |
title_fullStr | Intermolecular forces involving the water molecules in lithium sulfate monohydrate |
title_full_unstemmed | Intermolecular forces involving the water molecules in lithium sulfate monohydrate |
title_short | Intermolecular forces involving the water molecules in lithium sulfate monohydrate |
title_sort | intermolecular forces involving the water molecules in lithium sulfate monohydrate |
title_unstemmed | Intermolecular forces involving the water molecules in lithium sulfate monohydrate |
topic | Physical and Theoretical Chemistry, General Physics and Astronomy |
url | http://dx.doi.org/10.1063/1.432027 |