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Proton Transfer from H3+ to Unsaturated Hydrocarbons and to Cyclopropane
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| Zeitschriftentitel: | The Journal of Chemical Physics |
|---|---|
| Personen und Körperschaften: | , |
| In: | The Journal of Chemical Physics, 44, 1966, 9, S. 3574-3580 |
| Format: | E-Article |
| Sprache: | Englisch |
| veröffentlicht: |
AIP Publishing
|
| Schlagwörter: |
| author_facet |
Aquilanti, V. Volpi, G. G. Aquilanti, V. Volpi, G. G. |
|---|---|
| author |
Aquilanti, V. Volpi, G. G. |
| spellingShingle |
Aquilanti, V. Volpi, G. G. The Journal of Chemical Physics Proton Transfer from H3+ to Unsaturated Hydrocarbons and to Cyclopropane Physical and Theoretical Chemistry General Physics and Astronomy |
| author_sort |
aquilanti, v. |
| spelling |
Aquilanti, V. Volpi, G. G. 0021-9606 1089-7690 AIP Publishing Physical and Theoretical Chemistry General Physics and Astronomy http://dx.doi.org/10.1063/1.1727267 <jats:p>The ion—molecule reactions which H3+ and D3+ ions undergo with acetylene, methylacetylene, ethylene, propylene, and cyclopropane have been investigated by high-pressure mass spectrometry, and the rate constants have been measured. In all cases, proton (or deuteron) transfer from H3+ (or D3+) to the hydrocarbons occurs, and leads to the formation of excited ions which may either be stabilized by collision or decompose in smaller fragments when energy requirements are satisfied. Several kinetic parameters are assessed. Reactivity data for some ions with hydrogen, deuterium, and hydrocarbons are also reported.</jats:p> Proton Transfer from H3+ to Unsaturated Hydrocarbons and to Cyclopropane The Journal of Chemical Physics |
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AIP Publishing, 1966 |
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1966 |
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The Journal of Chemical Physics |
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49 |
| title |
Proton Transfer from H3+ to Unsaturated Hydrocarbons and to Cyclopropane |
| title_unstemmed |
Proton Transfer from H3+ to Unsaturated Hydrocarbons and to Cyclopropane |
| title_full |
Proton Transfer from H3+ to Unsaturated Hydrocarbons and to Cyclopropane |
| title_fullStr |
Proton Transfer from H3+ to Unsaturated Hydrocarbons and to Cyclopropane |
| title_full_unstemmed |
Proton Transfer from H3+ to Unsaturated Hydrocarbons and to Cyclopropane |
| title_short |
Proton Transfer from H3+ to Unsaturated Hydrocarbons and to Cyclopropane |
| title_sort |
proton transfer from h3+ to unsaturated hydrocarbons and to cyclopropane |
| topic |
Physical and Theoretical Chemistry General Physics and Astronomy |
| url |
http://dx.doi.org/10.1063/1.1727267 |
| publishDate |
1966 |
| physical |
3574-3580 |
| description |
<jats:p>The ion—molecule reactions which H3+ and D3+ ions undergo with acetylene, methylacetylene, ethylene, propylene, and cyclopropane have been investigated by high-pressure mass spectrometry, and the rate constants have been measured. In all cases, proton (or deuteron) transfer from H3+ (or D3+) to the hydrocarbons occurs, and leads to the formation of excited ions which may either be stabilized by collision or decompose in smaller fragments when energy requirements are satisfied. Several kinetic parameters are assessed. Reactivity data for some ions with hydrogen, deuterium, and hydrocarbons are also reported.</jats:p> |
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| author | Aquilanti, V., Volpi, G. G. |
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| author_sort | aquilanti, v. |
| container_issue | 9 |
| container_start_page | 3574 |
| container_title | The Journal of Chemical Physics |
| container_volume | 44 |
| description | <jats:p>The ion—molecule reactions which H3+ and D3+ ions undergo with acetylene, methylacetylene, ethylene, propylene, and cyclopropane have been investigated by high-pressure mass spectrometry, and the rate constants have been measured. In all cases, proton (or deuteron) transfer from H3+ (or D3+) to the hydrocarbons occurs, and leads to the formation of excited ions which may either be stabilized by collision or decompose in smaller fragments when energy requirements are satisfied. Several kinetic parameters are assessed. Reactivity data for some ions with hydrogen, deuterium, and hydrocarbons are also reported.</jats:p> |
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| id | ai-49-aHR0cDovL2R4LmRvaS5vcmcvMTAuMTA2My8xLjE3MjcyNjc |
| imprint | AIP Publishing, 1966 |
| imprint_str_mv | AIP Publishing, 1966 |
| institution | DE-D161, DE-Gla1, DE-Zi4, DE-15, DE-Pl11, DE-Rs1, DE-105, DE-14, DE-Ch1, DE-L229, DE-D275, DE-Bn3, DE-Brt1 |
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| physical | 3574-3580 |
| publishDate | 1966 |
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| publisher | AIP Publishing |
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| recordtype | ai |
| series | The Journal of Chemical Physics |
| source_id | 49 |
| spelling | Aquilanti, V. Volpi, G. G. 0021-9606 1089-7690 AIP Publishing Physical and Theoretical Chemistry General Physics and Astronomy http://dx.doi.org/10.1063/1.1727267 <jats:p>The ion—molecule reactions which H3+ and D3+ ions undergo with acetylene, methylacetylene, ethylene, propylene, and cyclopropane have been investigated by high-pressure mass spectrometry, and the rate constants have been measured. In all cases, proton (or deuteron) transfer from H3+ (or D3+) to the hydrocarbons occurs, and leads to the formation of excited ions which may either be stabilized by collision or decompose in smaller fragments when energy requirements are satisfied. Several kinetic parameters are assessed. Reactivity data for some ions with hydrogen, deuterium, and hydrocarbons are also reported.</jats:p> Proton Transfer from H3+ to Unsaturated Hydrocarbons and to Cyclopropane The Journal of Chemical Physics |
| spellingShingle | Aquilanti, V., Volpi, G. G., The Journal of Chemical Physics, Proton Transfer from H3+ to Unsaturated Hydrocarbons and to Cyclopropane, Physical and Theoretical Chemistry, General Physics and Astronomy |
| title | Proton Transfer from H3+ to Unsaturated Hydrocarbons and to Cyclopropane |
| title_full | Proton Transfer from H3+ to Unsaturated Hydrocarbons and to Cyclopropane |
| title_fullStr | Proton Transfer from H3+ to Unsaturated Hydrocarbons and to Cyclopropane |
| title_full_unstemmed | Proton Transfer from H3+ to Unsaturated Hydrocarbons and to Cyclopropane |
| title_short | Proton Transfer from H3+ to Unsaturated Hydrocarbons and to Cyclopropane |
| title_sort | proton transfer from h3+ to unsaturated hydrocarbons and to cyclopropane |
| title_unstemmed | Proton Transfer from H3+ to Unsaturated Hydrocarbons and to Cyclopropane |
| topic | Physical and Theoretical Chemistry, General Physics and Astronomy |
| url | http://dx.doi.org/10.1063/1.1727267 |