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Structures of the Alkyl Ions Produced in the Reactions between H3+ and Propane or Butanes
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| Zeitschriftentitel: | The Journal of Chemical Physics |
|---|---|
| Personen und Körperschaften: | , , , |
| In: | The Journal of Chemical Physics, 48, 1968, 9, S. 4310-4313 |
| Format: | E-Article |
| Sprache: | Englisch |
| veröffentlicht: |
AIP Publishing
|
| Schlagwörter: |
| author_facet |
Aquilanti, V. Galli, A. Giardini-Guidoni, A. Volpi, G. G. Aquilanti, V. Galli, A. Giardini-Guidoni, A. Volpi, G. G. |
|---|---|
| author |
Aquilanti, V. Galli, A. Giardini-Guidoni, A. Volpi, G. G. |
| spellingShingle |
Aquilanti, V. Galli, A. Giardini-Guidoni, A. Volpi, G. G. The Journal of Chemical Physics Structures of the Alkyl Ions Produced in the Reactions between H3+ and Propane or Butanes Physical and Theoretical Chemistry General Physics and Astronomy |
| author_sort |
aquilanti, v. |
| spelling |
Aquilanti, V. Galli, A. Giardini-Guidoni, A. Volpi, G. G. 0021-9606 1089-7690 AIP Publishing Physical and Theoretical Chemistry General Physics and Astronomy http://dx.doi.org/10.1063/1.1669775 <jats:p>The structures of the alkyl ions produced in the reactions of H3+ ions with propane or the butanes, H3+ + C2nH2n + 2→C2nH2n + 1+ + 2H2 and H3+ + C2nH2n + 2→CmH2m + 1+ + Cn − mH2(n − m) + 2 + H2, have been determined by high-pressure mass spectrometry, using deuterium-labeled hydrocarbons. Reactions (1) and (2) take place by exothermic rupture of a C–H and a C–C bond, respectively, without reshufflings of hydrogen atoms or rearrangements in the carbon skeleton. Information is also obtained about the alkyl ions involved in the reactions CmH2m + 1+ + CnH2n + 2→CnH2n + 1+ + +CmH2m + 2.</jats:p> Structures of the Alkyl Ions Produced in the Reactions between H3+ and Propane or Butanes The Journal of Chemical Physics |
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The Journal of Chemical Physics |
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| title |
Structures of the Alkyl Ions Produced in the Reactions between H3+ and Propane or Butanes |
| title_unstemmed |
Structures of the Alkyl Ions Produced in the Reactions between H3+ and Propane or Butanes |
| title_full |
Structures of the Alkyl Ions Produced in the Reactions between H3+ and Propane or Butanes |
| title_fullStr |
Structures of the Alkyl Ions Produced in the Reactions between H3+ and Propane or Butanes |
| title_full_unstemmed |
Structures of the Alkyl Ions Produced in the Reactions between H3+ and Propane or Butanes |
| title_short |
Structures of the Alkyl Ions Produced in the Reactions between H3+ and Propane or Butanes |
| title_sort |
structures of the alkyl ions produced in the reactions between h3+ and propane or butanes |
| topic |
Physical and Theoretical Chemistry General Physics and Astronomy |
| url |
http://dx.doi.org/10.1063/1.1669775 |
| publishDate |
1968 |
| physical |
4310-4313 |
| description |
<jats:p>The structures of the alkyl ions produced in the reactions of H3+ ions with propane or the butanes, H3+ + C2nH2n + 2→C2nH2n + 1+ + 2H2 and H3+ + C2nH2n + 2→CmH2m + 1+ + Cn − mH2(n − m) + 2 + H2, have been determined by high-pressure mass spectrometry, using deuterium-labeled hydrocarbons. Reactions (1) and (2) take place by exothermic rupture of a C–H and a C–C bond, respectively, without reshufflings of hydrogen atoms or rearrangements in the carbon skeleton. Information is also obtained about the alkyl ions involved in the reactions CmH2m + 1+ + CnH2n + 2→CnH2n + 1+ + +CmH2m + 2.</jats:p> |
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| author | Aquilanti, V., Galli, A., Giardini-Guidoni, A., Volpi, G. G. |
| author_facet | Aquilanti, V., Galli, A., Giardini-Guidoni, A., Volpi, G. G., Aquilanti, V., Galli, A., Giardini-Guidoni, A., Volpi, G. G. |
| author_sort | aquilanti, v. |
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| description | <jats:p>The structures of the alkyl ions produced in the reactions of H3+ ions with propane or the butanes, H3+ + C2nH2n + 2→C2nH2n + 1+ + 2H2 and H3+ + C2nH2n + 2→CmH2m + 1+ + Cn − mH2(n − m) + 2 + H2, have been determined by high-pressure mass spectrometry, using deuterium-labeled hydrocarbons. Reactions (1) and (2) take place by exothermic rupture of a C–H and a C–C bond, respectively, without reshufflings of hydrogen atoms or rearrangements in the carbon skeleton. Information is also obtained about the alkyl ions involved in the reactions CmH2m + 1+ + CnH2n + 2→CnH2n + 1+ + +CmH2m + 2.</jats:p> |
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| imprint | AIP Publishing, 1968 |
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| institution | DE-D275, DE-Bn3, DE-Brt1, DE-D161, DE-Gla1, DE-Zi4, DE-15, DE-Rs1, DE-Pl11, DE-105, DE-14, DE-Ch1, DE-L229 |
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| physical | 4310-4313 |
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| series | The Journal of Chemical Physics |
| source_id | 49 |
| spelling | Aquilanti, V. Galli, A. Giardini-Guidoni, A. Volpi, G. G. 0021-9606 1089-7690 AIP Publishing Physical and Theoretical Chemistry General Physics and Astronomy http://dx.doi.org/10.1063/1.1669775 <jats:p>The structures of the alkyl ions produced in the reactions of H3+ ions with propane or the butanes, H3+ + C2nH2n + 2→C2nH2n + 1+ + 2H2 and H3+ + C2nH2n + 2→CmH2m + 1+ + Cn − mH2(n − m) + 2 + H2, have been determined by high-pressure mass spectrometry, using deuterium-labeled hydrocarbons. Reactions (1) and (2) take place by exothermic rupture of a C–H and a C–C bond, respectively, without reshufflings of hydrogen atoms or rearrangements in the carbon skeleton. Information is also obtained about the alkyl ions involved in the reactions CmH2m + 1+ + CnH2n + 2→CnH2n + 1+ + +CmH2m + 2.</jats:p> Structures of the Alkyl Ions Produced in the Reactions between H3+ and Propane or Butanes The Journal of Chemical Physics |
| spellingShingle | Aquilanti, V., Galli, A., Giardini-Guidoni, A., Volpi, G. G., The Journal of Chemical Physics, Structures of the Alkyl Ions Produced in the Reactions between H3+ and Propane or Butanes, Physical and Theoretical Chemistry, General Physics and Astronomy |
| title | Structures of the Alkyl Ions Produced in the Reactions between H3+ and Propane or Butanes |
| title_full | Structures of the Alkyl Ions Produced in the Reactions between H3+ and Propane or Butanes |
| title_fullStr | Structures of the Alkyl Ions Produced in the Reactions between H3+ and Propane or Butanes |
| title_full_unstemmed | Structures of the Alkyl Ions Produced in the Reactions between H3+ and Propane or Butanes |
| title_short | Structures of the Alkyl Ions Produced in the Reactions between H3+ and Propane or Butanes |
| title_sort | structures of the alkyl ions produced in the reactions between h3+ and propane or butanes |
| title_unstemmed | Structures of the Alkyl Ions Produced in the Reactions between H3+ and Propane or Butanes |
| topic | Physical and Theoretical Chemistry, General Physics and Astronomy |
| url | http://dx.doi.org/10.1063/1.1669775 |