Eintrag weiter verarbeiten
Cobalt–benzene cluster anions: Mass spectrometry and negative ion photoelectron spectroscopy
Gespeichert in:
| Zeitschriftentitel: | The Journal of Chemical Physics |
|---|---|
| Personen und Körperschaften: | , , , , |
| In: | The Journal of Chemical Physics, 116, 2002, 23, S. 10247-10252 |
| Format: | E-Article |
| Sprache: | Englisch |
| veröffentlicht: |
AIP Publishing
|
| Schlagwörter: |
| author_facet |
Gerhards, M. Thomas, O. C. Nilles, J. M. Zheng, W.-J. Bowen, K. H. Gerhards, M. Thomas, O. C. Nilles, J. M. Zheng, W.-J. Bowen, K. H. |
|---|---|
| author |
Gerhards, M. Thomas, O. C. Nilles, J. M. Zheng, W.-J. Bowen, K. H. |
| spellingShingle |
Gerhards, M. Thomas, O. C. Nilles, J. M. Zheng, W.-J. Bowen, K. H. The Journal of Chemical Physics Cobalt–benzene cluster anions: Mass spectrometry and negative ion photoelectron spectroscopy Physical and Theoretical Chemistry General Physics and Astronomy |
| author_sort |
gerhards, m. |
| spelling |
Gerhards, M. Thomas, O. C. Nilles, J. M. Zheng, W.-J. Bowen, K. H. 0021-9606 1089-7690 AIP Publishing Physical and Theoretical Chemistry General Physics and Astronomy http://dx.doi.org/10.1063/1.1477924 <jats:p>( Cobalt ) n ( benzene ) m − cluster anions, (n,m) were generated by laser vaporization and studied by both mass spectrometry and anion photoelectron spectroscopy. Our assignment of the photoelectron spectrum of the (1,2) cluster anion suggests that it possesses a sandwich structure with the cobalt atom located between two parallel benzene rings, that the ground state of this anion is a singlet, and that the ground state of its corresponding neutral is a doublet. The photoelectron spectra of cobalt-rich cluster anions of the form (n,1) are interpreted as cobalt metal cluster anions which have been solvent-stabilized by their interaction with, in each case, a single benzene molecule. The photoelectron spectra of the benzene-rich cluster anions, (2,3), (2,2), and (3,3), are tentatively interpreted as suggesting extended sandwich structures for these anion complexes.</jats:p> Cobalt–benzene cluster anions: Mass spectrometry and negative ion photoelectron spectroscopy The Journal of Chemical Physics |
| doi_str_mv |
10.1063/1.1477924 |
| facet_avail |
Online |
| finc_class_facet |
Chemie und Pharmazie Physik |
| format |
ElectronicArticle |
| fullrecord |
blob:ai-49-aHR0cDovL2R4LmRvaS5vcmcvMTAuMTA2My8xLjE0Nzc5MjQ |
| id |
ai-49-aHR0cDovL2R4LmRvaS5vcmcvMTAuMTA2My8xLjE0Nzc5MjQ |
| institution |
DE-Gla1 DE-Zi4 DE-15 DE-Pl11 DE-Rs1 DE-105 DE-14 DE-Ch1 DE-L229 DE-D275 DE-Bn3 DE-Brt1 DE-D161 |
| imprint |
AIP Publishing, 2002 |
| imprint_str_mv |
AIP Publishing, 2002 |
| issn |
0021-9606 1089-7690 |
| issn_str_mv |
0021-9606 1089-7690 |
| language |
English |
| mega_collection |
AIP Publishing (CrossRef) |
| match_str |
gerhards2002cobaltbenzeneclusteranionsmassspectrometryandnegativeionphotoelectronspectroscopy |
| publishDateSort |
2002 |
| publisher |
AIP Publishing |
| recordtype |
ai |
| record_format |
ai |
| series |
The Journal of Chemical Physics |
| source_id |
49 |
| title |
Cobalt–benzene cluster anions: Mass spectrometry and negative ion photoelectron spectroscopy |
| title_unstemmed |
Cobalt–benzene cluster anions: Mass spectrometry and negative ion photoelectron spectroscopy |
| title_full |
Cobalt–benzene cluster anions: Mass spectrometry and negative ion photoelectron spectroscopy |
| title_fullStr |
Cobalt–benzene cluster anions: Mass spectrometry and negative ion photoelectron spectroscopy |
| title_full_unstemmed |
Cobalt–benzene cluster anions: Mass spectrometry and negative ion photoelectron spectroscopy |
| title_short |
Cobalt–benzene cluster anions: Mass spectrometry and negative ion photoelectron spectroscopy |
| title_sort |
cobalt–benzene cluster anions: mass spectrometry and negative ion photoelectron spectroscopy |
| topic |
Physical and Theoretical Chemistry General Physics and Astronomy |
| url |
http://dx.doi.org/10.1063/1.1477924 |
| publishDate |
2002 |
| physical |
10247-10252 |
| description |
<jats:p>( Cobalt ) n ( benzene ) m − cluster anions, (n,m) were generated by laser vaporization and studied by both mass spectrometry and anion photoelectron spectroscopy. Our assignment of the photoelectron spectrum of the (1,2) cluster anion suggests that it possesses a sandwich structure with the cobalt atom located between two parallel benzene rings, that the ground state of this anion is a singlet, and that the ground state of its corresponding neutral is a doublet. The photoelectron spectra of cobalt-rich cluster anions of the form (n,1) are interpreted as cobalt metal cluster anions which have been solvent-stabilized by their interaction with, in each case, a single benzene molecule. The photoelectron spectra of the benzene-rich cluster anions, (2,3), (2,2), and (3,3), are tentatively interpreted as suggesting extended sandwich structures for these anion complexes.</jats:p> |
| container_issue |
23 |
| container_start_page |
10247 |
| container_title |
The Journal of Chemical Physics |
| container_volume |
116 |
| format_de105 |
Article, E-Article |
| format_de14 |
Article, E-Article |
| format_de15 |
Article, E-Article |
| format_de520 |
Article, E-Article |
| format_de540 |
Article, E-Article |
| format_dech1 |
Article, E-Article |
| format_ded117 |
Article, E-Article |
| format_degla1 |
E-Article |
| format_del152 |
Buch |
| format_del189 |
Article, E-Article |
| format_dezi4 |
Article |
| format_dezwi2 |
Article, E-Article |
| format_finc |
Article, E-Article |
| format_nrw |
Article, E-Article |
| _version_ |
1792342477612515330 |
| geogr_code |
not assigned |
| last_indexed |
2024-03-01T16:36:25.122Z |
| geogr_code_person |
not assigned |
| openURL |
url_ver=Z39.88-2004&ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fvufind.svn.sourceforge.net%3Agenerator&rft.title=Cobalt%E2%80%93benzene+cluster+anions%3A+Mass+spectrometry+and+negative+ion+photoelectron+spectroscopy&rft.date=2002-06-15&genre=article&issn=1089-7690&volume=116&issue=23&spage=10247&epage=10252&pages=10247-10252&jtitle=The+Journal+of+Chemical+Physics&atitle=Cobalt%E2%80%93benzene+cluster+anions%3A+Mass+spectrometry+and+negative+ion+photoelectron+spectroscopy&aulast=Bowen&aufirst=K.+H.&rft_id=info%3Adoi%2F10.1063%2F1.1477924&rft.language%5B0%5D=eng |
| SOLR | |
| _version_ | 1792342477612515330 |
| author | Gerhards, M., Thomas, O. C., Nilles, J. M., Zheng, W.-J., Bowen, K. H. |
| author_facet | Gerhards, M., Thomas, O. C., Nilles, J. M., Zheng, W.-J., Bowen, K. H., Gerhards, M., Thomas, O. C., Nilles, J. M., Zheng, W.-J., Bowen, K. H. |
| author_sort | gerhards, m. |
| container_issue | 23 |
| container_start_page | 10247 |
| container_title | The Journal of Chemical Physics |
| container_volume | 116 |
| description | <jats:p>( Cobalt ) n ( benzene ) m − cluster anions, (n,m) were generated by laser vaporization and studied by both mass spectrometry and anion photoelectron spectroscopy. Our assignment of the photoelectron spectrum of the (1,2) cluster anion suggests that it possesses a sandwich structure with the cobalt atom located between two parallel benzene rings, that the ground state of this anion is a singlet, and that the ground state of its corresponding neutral is a doublet. The photoelectron spectra of cobalt-rich cluster anions of the form (n,1) are interpreted as cobalt metal cluster anions which have been solvent-stabilized by their interaction with, in each case, a single benzene molecule. The photoelectron spectra of the benzene-rich cluster anions, (2,3), (2,2), and (3,3), are tentatively interpreted as suggesting extended sandwich structures for these anion complexes.</jats:p> |
| doi_str_mv | 10.1063/1.1477924 |
| facet_avail | Online |
| finc_class_facet | Chemie und Pharmazie, Physik |
| format | ElectronicArticle |
| format_de105 | Article, E-Article |
| format_de14 | Article, E-Article |
| format_de15 | Article, E-Article |
| format_de520 | Article, E-Article |
| format_de540 | Article, E-Article |
| format_dech1 | Article, E-Article |
| format_ded117 | Article, E-Article |
| format_degla1 | E-Article |
| format_del152 | Buch |
| format_del189 | Article, E-Article |
| format_dezi4 | Article |
| format_dezwi2 | Article, E-Article |
| format_finc | Article, E-Article |
| format_nrw | Article, E-Article |
| geogr_code | not assigned |
| geogr_code_person | not assigned |
| id | ai-49-aHR0cDovL2R4LmRvaS5vcmcvMTAuMTA2My8xLjE0Nzc5MjQ |
| imprint | AIP Publishing, 2002 |
| imprint_str_mv | AIP Publishing, 2002 |
| institution | DE-Gla1, DE-Zi4, DE-15, DE-Pl11, DE-Rs1, DE-105, DE-14, DE-Ch1, DE-L229, DE-D275, DE-Bn3, DE-Brt1, DE-D161 |
| issn | 0021-9606, 1089-7690 |
| issn_str_mv | 0021-9606, 1089-7690 |
| language | English |
| last_indexed | 2024-03-01T16:36:25.122Z |
| match_str | gerhards2002cobaltbenzeneclusteranionsmassspectrometryandnegativeionphotoelectronspectroscopy |
| mega_collection | AIP Publishing (CrossRef) |
| physical | 10247-10252 |
| publishDate | 2002 |
| publishDateSort | 2002 |
| publisher | AIP Publishing |
| record_format | ai |
| recordtype | ai |
| series | The Journal of Chemical Physics |
| source_id | 49 |
| spelling | Gerhards, M. Thomas, O. C. Nilles, J. M. Zheng, W.-J. Bowen, K. H. 0021-9606 1089-7690 AIP Publishing Physical and Theoretical Chemistry General Physics and Astronomy http://dx.doi.org/10.1063/1.1477924 <jats:p>( Cobalt ) n ( benzene ) m − cluster anions, (n,m) were generated by laser vaporization and studied by both mass spectrometry and anion photoelectron spectroscopy. Our assignment of the photoelectron spectrum of the (1,2) cluster anion suggests that it possesses a sandwich structure with the cobalt atom located between two parallel benzene rings, that the ground state of this anion is a singlet, and that the ground state of its corresponding neutral is a doublet. The photoelectron spectra of cobalt-rich cluster anions of the form (n,1) are interpreted as cobalt metal cluster anions which have been solvent-stabilized by their interaction with, in each case, a single benzene molecule. The photoelectron spectra of the benzene-rich cluster anions, (2,3), (2,2), and (3,3), are tentatively interpreted as suggesting extended sandwich structures for these anion complexes.</jats:p> Cobalt–benzene cluster anions: Mass spectrometry and negative ion photoelectron spectroscopy The Journal of Chemical Physics |
| spellingShingle | Gerhards, M., Thomas, O. C., Nilles, J. M., Zheng, W.-J., Bowen, K. H., The Journal of Chemical Physics, Cobalt–benzene cluster anions: Mass spectrometry and negative ion photoelectron spectroscopy, Physical and Theoretical Chemistry, General Physics and Astronomy |
| title | Cobalt–benzene cluster anions: Mass spectrometry and negative ion photoelectron spectroscopy |
| title_full | Cobalt–benzene cluster anions: Mass spectrometry and negative ion photoelectron spectroscopy |
| title_fullStr | Cobalt–benzene cluster anions: Mass spectrometry and negative ion photoelectron spectroscopy |
| title_full_unstemmed | Cobalt–benzene cluster anions: Mass spectrometry and negative ion photoelectron spectroscopy |
| title_short | Cobalt–benzene cluster anions: Mass spectrometry and negative ion photoelectron spectroscopy |
| title_sort | cobalt–benzene cluster anions: mass spectrometry and negative ion photoelectron spectroscopy |
| title_unstemmed | Cobalt–benzene cluster anions: Mass spectrometry and negative ion photoelectron spectroscopy |
| topic | Physical and Theoretical Chemistry, General Physics and Astronomy |
| url | http://dx.doi.org/10.1063/1.1477924 |