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245 |a Polarity‐Switchable Symmetric Graphite Batteries with High Energy and High Power Densities 
264 |a Weinheim  |b WILEY‐VCH  |c 2018 
533 |a Online-Ausg.  |d 2019  |e Online-Ressource (Text)  |f Technische Universität Dresden 
520 |a Multifunctional batteries with enhanced safety performance have received considerable attention for their applications at extreme conditions. However, few batteries can endure a mix‐up of battery polarity during charging, a common wrong operation of rechargeable batteries. Herein, a polarity‐switchable battery based on the switchable intercalation feature of graphite is demonstrated. The unique redox‐amphoteric intercalation behavior of graphite allows a reversible switching of graphite between anode and cathode, thus enabling polarity‐switchable symmetric graphite batteries. The large potential gap between anion and cation intercalation delivers a high midpoint device voltage (≈average voltage) of ≈4.5 V. Further, both the graphite anode and cathode are kinetically activated during the polarity switching. Consequently, polarity‐switchable symmetric graphite batteries exhibit a remarkable cycling stability (96% capacity retention after 500 cycles), a high power density of 8.66 kW kg−1, and a high energy density of 227 Wh kg−1 (calculated based on the total weight of active materials in both anode and cathode), which are superior to other symmetric batteries and recently reported dual‐graphite or dual‐carbon batteries. This work will inspire the development of new multifunctional energy‐storage devices based on novel materials and electrolyte systems. 
650 |a Dual‐Graphite Batteries 
650 |a Dual‐Ion Batteries 
650 |a Multifunctional Batteries 
650 |a Polarity Switchability 
650 |a Dual-Graphit-Batterien 
650 |a Dual-Ionen-Batterien 
650 |a Multifunktionsbatterien 
650 |a Polaritätsumschaltbarkeit 
700 |a Wang, Faxing 
700 |a Zhang, Panpan 
700 |a Zhang, Jian 
700 |a Zhang, Tao 
700 |a Müllen, Klaus 
700 |a Feng, Xinliang 
773 |g 30,2018,39 
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author Wang, Gang
author2 Wang, Faxing, Zhang, Panpan, Zhang, Jian, Zhang, Tao, Müllen, Klaus, Feng, Xinliang
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contents Multifunctional batteries with enhanced safety performance have received considerable attention for their applications at extreme conditions. However, few batteries can endure a mix‐up of battery polarity during charging, a common wrong operation of rechargeable batteries. Herein, a polarity‐switchable battery based on the switchable intercalation feature of graphite is demonstrated. The unique redox‐amphoteric intercalation behavior of graphite allows a reversible switching of graphite between anode and cathode, thus enabling polarity‐switchable symmetric graphite batteries. The large potential gap between anion and cation intercalation delivers a high midpoint device voltage (≈average voltage) of ≈4.5 V. Further, both the graphite anode and cathode are kinetically activated during the polarity switching. Consequently, polarity‐switchable symmetric graphite batteries exhibit a remarkable cycling stability (96% capacity retention after 500 cycles), a high power density of 8.66 kW kg−1, and a high energy density of 227 Wh kg−1 (calculated based on the total weight of active materials in both anode and cathode), which are superior to other symmetric batteries and recently reported dual‐graphite or dual‐carbon batteries. This work will inspire the development of new multifunctional energy‐storage devices based on novel materials and electrolyte systems.
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spelling Wang, Gang, Polarity‐Switchable Symmetric Graphite Batteries with High Energy and High Power Densities, Weinheim WILEY‐VCH 2018, Online-Ausg. 2019 Online-Ressource (Text) Technische Universität Dresden, Multifunctional batteries with enhanced safety performance have received considerable attention for their applications at extreme conditions. However, few batteries can endure a mix‐up of battery polarity during charging, a common wrong operation of rechargeable batteries. Herein, a polarity‐switchable battery based on the switchable intercalation feature of graphite is demonstrated. The unique redox‐amphoteric intercalation behavior of graphite allows a reversible switching of graphite between anode and cathode, thus enabling polarity‐switchable symmetric graphite batteries. The large potential gap between anion and cation intercalation delivers a high midpoint device voltage (≈average voltage) of ≈4.5 V. Further, both the graphite anode and cathode are kinetically activated during the polarity switching. Consequently, polarity‐switchable symmetric graphite batteries exhibit a remarkable cycling stability (96% capacity retention after 500 cycles), a high power density of 8.66 kW kg−1, and a high energy density of 227 Wh kg−1 (calculated based on the total weight of active materials in both anode and cathode), which are superior to other symmetric batteries and recently reported dual‐graphite or dual‐carbon batteries. This work will inspire the development of new multifunctional energy‐storage devices based on novel materials and electrolyte systems., Dual‐Graphite Batteries, Dual‐Ion Batteries, Multifunctional Batteries, Polarity Switchability, Dual-Graphit-Batterien, Dual-Ionen-Batterien, Multifunktionsbatterien, Polaritätsumschaltbarkeit, Wang, Faxing, Zhang, Panpan, Zhang, Jian, Zhang, Tao, Müllen, Klaus, Feng, Xinliang, 30,2018,39, text/html https://nbn-resolving.org/urn:nbn:de:bsz:14-qucosa2-345643 Online-Zugriff
spellingShingle Wang, Gang, Polarity‐Switchable Symmetric Graphite Batteries with High Energy and High Power Densities, Multifunctional batteries with enhanced safety performance have received considerable attention for their applications at extreme conditions. However, few batteries can endure a mix‐up of battery polarity during charging, a common wrong operation of rechargeable batteries. Herein, a polarity‐switchable battery based on the switchable intercalation feature of graphite is demonstrated. The unique redox‐amphoteric intercalation behavior of graphite allows a reversible switching of graphite between anode and cathode, thus enabling polarity‐switchable symmetric graphite batteries. The large potential gap between anion and cation intercalation delivers a high midpoint device voltage (≈average voltage) of ≈4.5 V. Further, both the graphite anode and cathode are kinetically activated during the polarity switching. Consequently, polarity‐switchable symmetric graphite batteries exhibit a remarkable cycling stability (96% capacity retention after 500 cycles), a high power density of 8.66 kW kg−1, and a high energy density of 227 Wh kg−1 (calculated based on the total weight of active materials in both anode and cathode), which are superior to other symmetric batteries and recently reported dual‐graphite or dual‐carbon batteries. This work will inspire the development of new multifunctional energy‐storage devices based on novel materials and electrolyte systems., Dual‐Graphite Batteries, Dual‐Ion Batteries, Multifunctional Batteries, Polarity Switchability, Dual-Graphit-Batterien, Dual-Ionen-Batterien, Multifunktionsbatterien, Polaritätsumschaltbarkeit
title Polarity‐Switchable Symmetric Graphite Batteries with High Energy and High Power Densities
title_auth Polarity‐Switchable Symmetric Graphite Batteries with High Energy and High Power Densities
title_full Polarity‐Switchable Symmetric Graphite Batteries with High Energy and High Power Densities
title_fullStr Polarity‐Switchable Symmetric Graphite Batteries with High Energy and High Power Densities
title_full_unstemmed Polarity‐Switchable Symmetric Graphite Batteries with High Energy and High Power Densities
title_in_hierarchy
title_short Polarity‐Switchable Symmetric Graphite Batteries with High Energy and High Power Densities
title_sort polarity‐switchable symmetric graphite batteries with high energy and high power densities
title_unstemmed Polarity‐Switchable Symmetric Graphite Batteries with High Energy and High Power Densities
topic Dual‐Graphite Batteries, Dual‐Ion Batteries, Multifunctional Batteries, Polarity Switchability, Dual-Graphit-Batterien, Dual-Ionen-Batterien, Multifunktionsbatterien, Polaritätsumschaltbarkeit
topic_facet Dual‐Graphite Batteries, Dual‐Ion Batteries, Multifunctional Batteries, Polarity Switchability, Dual-Graphit-Batterien, Dual-Ionen-Batterien, Multifunktionsbatterien, Polaritätsumschaltbarkeit
url https://nbn-resolving.org/urn:nbn:de:bsz:14-qucosa2-345643
urn urn:nbn:de:bsz:14-qucosa2-345643
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