author_facet Zhou, Simon Ningsun
Reiner, Eric J.
Marvin, Chris H.
Helm, Paul A.
Shen, Li
Brindle, Ian D.
Zhou, Simon Ningsun
Reiner, Eric J.
Marvin, Chris H.
Helm, Paul A.
Shen, Li
Brindle, Ian D.
author Zhou, Simon Ningsun
Reiner, Eric J.
Marvin, Chris H.
Helm, Paul A.
Shen, Li
Brindle, Ian D.
spellingShingle Zhou, Simon Ningsun
Reiner, Eric J.
Marvin, Chris H.
Helm, Paul A.
Shen, Li
Brindle, Ian D.
Rapid Communications in Mass Spectrometry
Liquid chromatography/atmospheric pressure photoionization tandem mass spectrometry for analysis of Dechloranes
Organic Chemistry
Spectroscopy
Analytical Chemistry
author_sort zhou, simon ningsun
spelling Zhou, Simon Ningsun Reiner, Eric J. Marvin, Chris H. Helm, Paul A. Shen, Li Brindle, Ian D. 0951-4198 1097-0231 Wiley Organic Chemistry Spectroscopy Analytical Chemistry http://dx.doi.org/10.1002/rcm.4874 <jats:title>Abstract</jats:title><jats:p>Liquid chromatography/atmospheric pressure photoionization tandem mass spectrometry (LC/APPI‐MS/MS) was investigated as an instrumental method for the analysis of the halogenated norbornene flame retardants, Mirex, Dechloranes 602, 603, 604, and Dechlorane Plus (DP). The LC separation was optimized by screening a variety of stationary and mobile phases, resulting in a short LC separation time of 5 min. Different atmospheric pressure ionization approaches were examined including electrospray ionization, atmospheric pressure chemical ionization, and APPI, each with and without post‐column addition. APPI without post‐column addition was chosen for providing the best ionization response. The optimized LC/APPI‐MS/MS approach resulted in instrument detection limits ranging between 25 and 50 pg. Good linearity was also achieved (up to 25.0 ng/µL; <jats:italic>R</jats:italic> &gt;0.999). The method was applied to extracts of environmental samples including surface water, fish and sediments for screening purposes, and the results agreed well with those obtained by gas chromatography/mass spectrometry. Copyright © 2011 John Wiley &amp; Sons, Ltd.</jats:p> Liquid chromatography/atmospheric pressure photoionization tandem mass spectrometry for analysis of Dechloranes Rapid Communications in Mass Spectrometry
doi_str_mv 10.1002/rcm.4874
facet_avail Online
finc_class_facet Chemie und Pharmazie
Physik
format ElectronicArticle
fullrecord blob:ai-49-aHR0cDovL2R4LmRvaS5vcmcvMTAuMTAwMi9yY20uNDg3NA
id ai-49-aHR0cDovL2R4LmRvaS5vcmcvMTAuMTAwMi9yY20uNDg3NA
institution DE-Bn3
DE-Brt1
DE-D161
DE-Gla1
DE-Zi4
DE-15
DE-Pl11
DE-Rs1
DE-105
DE-14
DE-Ch1
DE-L229
DE-D275
imprint Wiley, 2011
imprint_str_mv Wiley, 2011
issn 0951-4198
1097-0231
issn_str_mv 0951-4198
1097-0231
language English
mega_collection Wiley (CrossRef)
match_str zhou2011liquidchromatographyatmosphericpressurephotoionizationtandemmassspectrometryforanalysisofdechloranes
publishDateSort 2011
publisher Wiley
recordtype ai
record_format ai
series Rapid Communications in Mass Spectrometry
source_id 49
title Liquid chromatography/atmospheric pressure photoionization tandem mass spectrometry for analysis of Dechloranes
title_unstemmed Liquid chromatography/atmospheric pressure photoionization tandem mass spectrometry for analysis of Dechloranes
title_full Liquid chromatography/atmospheric pressure photoionization tandem mass spectrometry for analysis of Dechloranes
title_fullStr Liquid chromatography/atmospheric pressure photoionization tandem mass spectrometry for analysis of Dechloranes
title_full_unstemmed Liquid chromatography/atmospheric pressure photoionization tandem mass spectrometry for analysis of Dechloranes
title_short Liquid chromatography/atmospheric pressure photoionization tandem mass spectrometry for analysis of Dechloranes
title_sort liquid chromatography/atmospheric pressure photoionization tandem mass spectrometry for analysis of dechloranes
topic Organic Chemistry
Spectroscopy
Analytical Chemistry
url http://dx.doi.org/10.1002/rcm.4874
publishDate 2011
physical 436-442
description <jats:title>Abstract</jats:title><jats:p>Liquid chromatography/atmospheric pressure photoionization tandem mass spectrometry (LC/APPI‐MS/MS) was investigated as an instrumental method for the analysis of the halogenated norbornene flame retardants, Mirex, Dechloranes 602, 603, 604, and Dechlorane Plus (DP). The LC separation was optimized by screening a variety of stationary and mobile phases, resulting in a short LC separation time of 5 min. Different atmospheric pressure ionization approaches were examined including electrospray ionization, atmospheric pressure chemical ionization, and APPI, each with and without post‐column addition. APPI without post‐column addition was chosen for providing the best ionization response. The optimized LC/APPI‐MS/MS approach resulted in instrument detection limits ranging between 25 and 50 pg. Good linearity was also achieved (up to 25.0 ng/µL; <jats:italic>R</jats:italic> &gt;0.999). The method was applied to extracts of environmental samples including surface water, fish and sediments for screening purposes, and the results agreed well with those obtained by gas chromatography/mass spectrometry. Copyright © 2011 John Wiley &amp; Sons, Ltd.</jats:p>
container_issue 3
container_start_page 436
container_title Rapid Communications in Mass Spectrometry
container_volume 25
format_de105 Article, E-Article
format_de14 Article, E-Article
format_de15 Article, E-Article
format_de520 Article, E-Article
format_de540 Article, E-Article
format_dech1 Article, E-Article
format_ded117 Article, E-Article
format_degla1 E-Article
format_del152 Buch
format_del189 Article, E-Article
format_dezi4 Article
format_dezwi2 Article, E-Article
format_finc Article, E-Article
format_nrw Article, E-Article
_version_ 1792335712632176646
geogr_code not assigned
last_indexed 2024-03-01T14:48:55.355Z
geogr_code_person not assigned
openURL url_ver=Z39.88-2004&ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fvufind.svn.sourceforge.net%3Agenerator&rft.title=Liquid+chromatography%2Fatmospheric+pressure+photoionization+tandem+mass+spectrometry+for+analysis+of+Dechloranes&rft.date=2011-02-15&genre=article&issn=1097-0231&volume=25&issue=3&spage=436&epage=442&pages=436-442&jtitle=Rapid+Communications+in+Mass+Spectrometry&atitle=Liquid+chromatography%2Fatmospheric+pressure+photoionization+tandem+mass+spectrometry+for+analysis+of+Dechloranes&aulast=Brindle&aufirst=Ian+D.&rft_id=info%3Adoi%2F10.1002%2Frcm.4874&rft.language%5B0%5D=eng
SOLR
_version_ 1792335712632176646
author Zhou, Simon Ningsun, Reiner, Eric J., Marvin, Chris H., Helm, Paul A., Shen, Li, Brindle, Ian D.
author_facet Zhou, Simon Ningsun, Reiner, Eric J., Marvin, Chris H., Helm, Paul A., Shen, Li, Brindle, Ian D., Zhou, Simon Ningsun, Reiner, Eric J., Marvin, Chris H., Helm, Paul A., Shen, Li, Brindle, Ian D.
author_sort zhou, simon ningsun
container_issue 3
container_start_page 436
container_title Rapid Communications in Mass Spectrometry
container_volume 25
description <jats:title>Abstract</jats:title><jats:p>Liquid chromatography/atmospheric pressure photoionization tandem mass spectrometry (LC/APPI‐MS/MS) was investigated as an instrumental method for the analysis of the halogenated norbornene flame retardants, Mirex, Dechloranes 602, 603, 604, and Dechlorane Plus (DP). The LC separation was optimized by screening a variety of stationary and mobile phases, resulting in a short LC separation time of 5 min. Different atmospheric pressure ionization approaches were examined including electrospray ionization, atmospheric pressure chemical ionization, and APPI, each with and without post‐column addition. APPI without post‐column addition was chosen for providing the best ionization response. The optimized LC/APPI‐MS/MS approach resulted in instrument detection limits ranging between 25 and 50 pg. Good linearity was also achieved (up to 25.0 ng/µL; <jats:italic>R</jats:italic> &gt;0.999). The method was applied to extracts of environmental samples including surface water, fish and sediments for screening purposes, and the results agreed well with those obtained by gas chromatography/mass spectrometry. Copyright © 2011 John Wiley &amp; Sons, Ltd.</jats:p>
doi_str_mv 10.1002/rcm.4874
facet_avail Online
finc_class_facet Chemie und Pharmazie, Physik
format ElectronicArticle
format_de105 Article, E-Article
format_de14 Article, E-Article
format_de15 Article, E-Article
format_de520 Article, E-Article
format_de540 Article, E-Article
format_dech1 Article, E-Article
format_ded117 Article, E-Article
format_degla1 E-Article
format_del152 Buch
format_del189 Article, E-Article
format_dezi4 Article
format_dezwi2 Article, E-Article
format_finc Article, E-Article
format_nrw Article, E-Article
geogr_code not assigned
geogr_code_person not assigned
id ai-49-aHR0cDovL2R4LmRvaS5vcmcvMTAuMTAwMi9yY20uNDg3NA
imprint Wiley, 2011
imprint_str_mv Wiley, 2011
institution DE-Bn3, DE-Brt1, DE-D161, DE-Gla1, DE-Zi4, DE-15, DE-Pl11, DE-Rs1, DE-105, DE-14, DE-Ch1, DE-L229, DE-D275
issn 0951-4198, 1097-0231
issn_str_mv 0951-4198, 1097-0231
language English
last_indexed 2024-03-01T14:48:55.355Z
match_str zhou2011liquidchromatographyatmosphericpressurephotoionizationtandemmassspectrometryforanalysisofdechloranes
mega_collection Wiley (CrossRef)
physical 436-442
publishDate 2011
publishDateSort 2011
publisher Wiley
record_format ai
recordtype ai
series Rapid Communications in Mass Spectrometry
source_id 49
spelling Zhou, Simon Ningsun Reiner, Eric J. Marvin, Chris H. Helm, Paul A. Shen, Li Brindle, Ian D. 0951-4198 1097-0231 Wiley Organic Chemistry Spectroscopy Analytical Chemistry http://dx.doi.org/10.1002/rcm.4874 <jats:title>Abstract</jats:title><jats:p>Liquid chromatography/atmospheric pressure photoionization tandem mass spectrometry (LC/APPI‐MS/MS) was investigated as an instrumental method for the analysis of the halogenated norbornene flame retardants, Mirex, Dechloranes 602, 603, 604, and Dechlorane Plus (DP). The LC separation was optimized by screening a variety of stationary and mobile phases, resulting in a short LC separation time of 5 min. Different atmospheric pressure ionization approaches were examined including electrospray ionization, atmospheric pressure chemical ionization, and APPI, each with and without post‐column addition. APPI without post‐column addition was chosen for providing the best ionization response. The optimized LC/APPI‐MS/MS approach resulted in instrument detection limits ranging between 25 and 50 pg. Good linearity was also achieved (up to 25.0 ng/µL; <jats:italic>R</jats:italic> &gt;0.999). The method was applied to extracts of environmental samples including surface water, fish and sediments for screening purposes, and the results agreed well with those obtained by gas chromatography/mass spectrometry. Copyright © 2011 John Wiley &amp; Sons, Ltd.</jats:p> Liquid chromatography/atmospheric pressure photoionization tandem mass spectrometry for analysis of Dechloranes Rapid Communications in Mass Spectrometry
spellingShingle Zhou, Simon Ningsun, Reiner, Eric J., Marvin, Chris H., Helm, Paul A., Shen, Li, Brindle, Ian D., Rapid Communications in Mass Spectrometry, Liquid chromatography/atmospheric pressure photoionization tandem mass spectrometry for analysis of Dechloranes, Organic Chemistry, Spectroscopy, Analytical Chemistry
title Liquid chromatography/atmospheric pressure photoionization tandem mass spectrometry for analysis of Dechloranes
title_full Liquid chromatography/atmospheric pressure photoionization tandem mass spectrometry for analysis of Dechloranes
title_fullStr Liquid chromatography/atmospheric pressure photoionization tandem mass spectrometry for analysis of Dechloranes
title_full_unstemmed Liquid chromatography/atmospheric pressure photoionization tandem mass spectrometry for analysis of Dechloranes
title_short Liquid chromatography/atmospheric pressure photoionization tandem mass spectrometry for analysis of Dechloranes
title_sort liquid chromatography/atmospheric pressure photoionization tandem mass spectrometry for analysis of dechloranes
title_unstemmed Liquid chromatography/atmospheric pressure photoionization tandem mass spectrometry for analysis of Dechloranes
topic Organic Chemistry, Spectroscopy, Analytical Chemistry
url http://dx.doi.org/10.1002/rcm.4874